HR job title
- Associate Professor
- Contact Info
- ORCiD
- 0000-0001-8151-7519
Gutierrez Santacruz, Osvaldo Associate Professor
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Overview
Publications
selected publications
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academic article
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Masson-Makdissi, J., Lalisse, R. F., Yuan, M., Dherange, B. D., Gutierrez, O., & Levin, M. D.
(2024).
Evidence for Dearomatizing Spirocyclization and Dynamic Effects in the Quasi-stereospecific Nitrogen Deletion of Tetrahydroisoquinolines. Journal of the American Chemical Society.
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Targos, K., Gogoi, A. R., ngel Rentera-Gmez, .., Kim, M. J., Gutierrez, O., & Wickens, Z. K.
(2024).
Mechanism of Z-Selective Allylic Functionalization via Thianthrenium Salts. Journal of the American Chemical Society.
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Laskar, R., Dutta, S., Spies, J. C., Mukherjee, P., Rentera-Gmez, . ., Thielemann, R. E., ... Glorius, F.
(2024).
-Amino Alcohols via Energy Transfer Enabled Brook Rearrangement. Journal of the American Chemical Society.
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Wu, D., Martin, R. T., Pia, J., Kwon, J., Crockett, M. P., Thomas, A. A., ... Campos, L. M.
(2024).
Cyclopropenimine-Mediated CO2 Activation for the Synthesis of Polyurethanes and Small-Molecule Carbonates and Carbamates. Angewandte Chemie International Edition.
e202401281.
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Mandal, H., Ogunyemi, O. J., Nicholson, J. L., Orr, M. E., Lalisse, R. F., Rentera-Gmez, . ., ... Goodson, T.
(2024).
Linear and Nonlinear Optical Properties of All-cis and All-trans Poly(p-phenylenevinylene). Journal of Physical Chemistry C.
128(6), 2518-2528.
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Alvarez, E. M., Stewart, G., Ullah, M., Lalisse, R., Gutierrez, O., & Malapit, C. A.
(2024).
Site-Selective Electrochemical Arene C-H Amination. Journal of the American Chemical Society.
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Wu, F., Chintawar, C. C., Lalisse, R., Mukherjee, P., Dutta, S., Tyler, J., ... Glorius, F.
(2024).
Ring expansion of indene by photoredox-enabled functionalized carbon-atom insertion. Nature Catalysis.
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Youshaw, C. R., Yang, M., Gogoi, A. R., Rentera-Gmez, A., Liu, L., Morehead, L. M., & Gutierrez, O.
(2023).
Iron-Catalyzed Enantioselective Multicomponent Cross-Couplings of -Boryl Radicals. Organic Letters.
25(46), 8320-8325.
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Yang, Y., Tsien, J., Dykstra, R., Chen, S., Wang, J. B., Merchant, R. R., ... Qin, T.
(2023).
Programmable late-stage functionalization of bridge-substituted bicyclo[1.1.1]pentane bis-boronates. Nature Chemistry.
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Andreetta, P., Martin, R. T., Souilah, C., Rentera-Gmez, . ., Song, Z., Khorramshahi Bayat, Y., ... Casitas, A.
(2023).
Experimental and Computational Studies on Cobalt(I)-Catalyzed Regioselective Allylic Alkylation Reactions. Angewandte Chemie International Edition.
e202310129.
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Rentera-Gmez, . ., Guerrero, M., Ramirez-Lopez, M., & Gutierrez, O.
(2023).
Regioselective Fluoroalkylarylation of Enamides Enabled by an Iron-Catalyzed Multicomponent Radical Cross-Coupling Strategy. Organic Letters.
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Aguilera, M. C., Gogoi, A. R., Lee, W., Liu, L., Brennessel, W. W., Gutierrez, O., & Neidig, M. L.
(2023).
Insight into Radical Initiation, Solvent Effects, and Biphenyl Production in Iron-Bisphosphine Cross-Couplings. ACS Catalysis.
13(13), 8987-8996.
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Crockett, M. P., Pia, J., Gogoi, A. R., Lalisse, R. F., Nguyen, A. V., Gutierrez, O., & Thomas, A. A.
(2023).
Breaking the tert-Butyllithium Contact Ion Pair: A Gateway to Alternate Selectivity in Lithiation Reactions. Journal of the American Chemical Society.
145(19), 10743-10755.
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Peng, Q., Gogoi, A. R., Rentera-Gmez, . ., Gutierrez, O., & Scheidt, K. A.
(2023).
Visible light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy. Chem.
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Zhou, M., Tsien, J., Dykstra, R., Hughes, J., Peters, B. K., Merchant, R. R., Gutierrez, O., & Qin, T.
(2023).
Alkyl sulfinates as cross-coupling partners for programmable and stereospecific installation of C(sp3) bioisosteres. Nature Chemistry.
15(4), 550-559.
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Day, C., Renteria-Gomez, A., Ton, S., Gogoi, A. R., Gutierrez, O., & Martin, R.
(2023).
Elucidating electron-transfer events in polypyridine nickel complexes for reductive coupling reactions. Nature Catalysis.
6(3), 244-253.
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Matsuo, B., Majhi, J., Granados, A., Sharique, M., Martin, R. T., Gutierrez, O., & Molander, G. A.
(2023).
Transition metal-free photochemical C-F activation for the preparation of difluorinated-oxindole derivatives. Chemical Science.
14(9), 2379-2385.
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Berger, K. J., Driscoll, J. L., Yuan, M., Dherange, B. D., Gutierrez, O., & Levin, M. D.
(2023).
Addition to "Direct Deamination of Primary Amines via Isodiazene Intermediates". Journal of the American Chemical Society.
145(1), 745-745.
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Dherange, B. D., Yuan, M., Kelly, C. B., Reiher, C. A., Grosanu, C., Berger, K. J., Gutierrez, O., & Levin, M. D.
(2023).
Direct Deaminative Functionalization. Journal of the American Chemical Society.
145(1), 17-24.
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Zhu, J. L., Schull, C. R., Tam, A. T., Rentera-Gmez, . ., Gogoi, A. R., Gutierrez, O., & Scheidt, K. A.
(2023).
Photoinduced Acylations Via Azolium-Promoted Intermolecular Hydrogen Atom Transfer. Journal of the American Chemical Society.
145(3), 1535-1541.
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Li, X., Yuan, M., Chen, F., Huang, Z., Qing, F., Gutierrez, O., & Chu, L.
(2023).
Three-component enantioselective alkenylation of organophosphonates via nickel metallaphotoredox catalysis. Chem.
9(1), 154-169.
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Dhungana, R. K., Granados, A., Ciccone, V., Martin, R. T., Majhi, J., Sharique, M., Gutierrez, O., & Molander, G. A.
(2022).
Trifunctionalization of Cinnamyl Alcohols Provides Access to Brominated alpha,alpha-Difluoro-gamma-lactones via a Photoinduced Radical-Polar-Radical Mechanism. ACS Catalysis.
12(24), 15750-15757.
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Tan, G., Paulus, F., Rentera-Gmez, . ., Lalisse, R. F., Daniliuc, C. G., Gutierrez, O., & Glorius, F.
(2022).
Highly Selective Radical Relay 1,4-Oxyimination of Two Electronically Differentiated Olefins. Journal of the American Chemical Society.
144(47), 21664-21673.
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Renteria-Gomez, A., Lee, W., Yin, S., Davis, M., Gogoi, A. R., & Gutierrez, O.
(2022).
General and Practical Route to Diverse 1-(Difluoro)alkyl-3-aryl Bicyclo[1.1.1]pentanes Enabled by an Fe-Catalyzed Multicomponent Radical Cross-Coupling Reaction. 12(19), 11547-11556.
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Majhi, J., Dhungana, R. K., Rentera-Gmez, . ., Sharique, M., Li, L., Dong, W., Gutierrez, O., & Molander, G. A.
(2022).
Metal-Free Photochemical Imino-Alkylation of Alkenes with Bifunctional Oxime Esters. Journal of the American Chemical Society.
144(34), 15871-15878.
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Wen, Y., Rentera-Gmez, . ., Day, G. S., Smith, M. F., Yan, T., Ozdemir, R., ... Zhou, H.
(2022).
Integrated Photocatalytic Reduction and Oxidation of Perfluorooctanoic Acid by Metal-Organic Frameworks: Key Insights into the Degradation Mechanisms. 144(26), 11840-11850.
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Yuan, M., & Gutierrez, O.
(2022).
Mechanisms, Challenges, and Opportunities of Dual Ni/Photoredox-Catalyzed C(sp2)-C(sp3) Cross-Couplings. 12(3), e1573.
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Wang, H., Liu, C., Martin, R. T., Gutierrez, O., & Koh, M. J.
(2022).
Author Correction: Directing-group-free catalytic dicarbofunctionalization of unactivated alkenes. Nature Chemistry.
14(2), 239-239.
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Altundas, B., Alwedi, E., Song, Z., Gogoi, A. R., Dykstra, R., Gutierrez, O., & Fleming, F. F.
(2022).
Dearomatization of aromatic asmic isocyanides to complex cyclohexadienes. Nature Communications.
13(1), 6444.
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Wang, H., Liu, C., Martin, R. T., Gutierrez, O., & Koh, M. J.
(2022).
Directing-group-free catalytic dicarbofunctionalization of unactivated alkenes. Nature Chemistry.
14(2), 188-195.
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Rotella, M. E., Sar, D., Liu, L., & Gutierrez, O.
(2021).
Fe-Catalyzed dicarbofunctionalization of electron-rich alkenes with Grignard reagents and (fluoro)alkyl halides. Chemical Communications.
57(93), 12508-12511.
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Berger, K. J., Driscoll, J. L., Yuan, M., Dherange, B. D., Gutierrez, O., & Levin, M. D.
(2021).
Direct Deamination of Primary Amines via Isodiazene Intermediates. Journal of the American Chemical Society.
143(42), 17366-17373.
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Liu, L., Aguilera, M. C., Lee, W., Youshaw, C. R., Neidig, M. L., & Gutierrez, O.
(2021).
General method for iron-catalyzed multicomponent radical cascades-cross-couplings. Science.
374(6566), 432-439.
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DeMuth, J. C., Song, Z., Carpenter, S. H., Boddie, T. E., Radovi, A., Baker, T. M., Gutierrez, O., & Neidig, M. L.
(2021).
Experimental and computational studies of the mechanism of iron-catalysed C-H activation/functionalisation with allyl electrophiles. Chemical Science.
12(27), 9398-9407.
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Thompson, R. R., Rotella, M. E., Zhou, X., Fronczek, F. R., Gutierrez, O., & Lee, S.
(2021).
Impact of Ligands and Metals on the Formation of Metallacyclic Intermediates and a Nontraditional Mechanism for Group VI Alkyne Metathesis Catalysts. Journal of the American Chemical Society.
143(24), 9026-9039.
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Agrawal, T., Martin, R. T., Collins, S., Wilhelm, Z., Edwards, M. D., Gutierrez, O., & Sieber, J. D.
(2021).
Access to Chiral Diamine Derivatives through Stereoselective Cu-Catalyzed Reductive Coupling of Imines and Allenamides. Journal of Organic Chemistry.
86(7), 5026-5046.
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Campbell, M. W., Yuan, M., Polites, V. C., Gutierrez, O., & Molander, G. A.
(2021).
Photochemical C-H Activation Enables Nickel-Catalyzed Olefin Dicarbofunctionalization. Journal of the American Chemical Society.
143(10), 3901-3910.
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Lipp, A., Badir, S. O., Dykstra, R., Gutierrez, O., & Molander, G. A.
(2021).
Catalyst-Free Decarbonylative Trifluoromethylthiolation Enabled by Electron Donor-Acceptor Complex Photoactivation. Advanced Synthesis and Catalysis.
363(14), 3507-3520.
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Liu, C., Wang, H., Martin, R. T., Zhao, H., Gutierrez, O., & Koh, M. J.
(2021).
Olefin Functionalization/Isomerization Enables Stereoselective Alkene Synthesis. Nature Catalysis.
4(8), 674-683.
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Guo, L., Yuan, M., Zhang, Y., Wang, F., Zhu, S., Gutierrez, O., & Chu, L.
(2020).
General Method for Enantioselective Three-Component Carboarylation of Alkenes Enabled by Visible-Light Dual Photoredox/Nickel Catalysis. Journal of the American Chemical Society.
142(48), 20390-20399.
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Liu, L., Lee, W., Youshaw, C. R., Yuan, M., Geherty, M. B., Zavalij, P. Y., & Gutierrez, O.
(2020).
Fe-catalyzed three-component dicarbofunctionalization of unactivated alkenes with alkyl halides and Grignard reagents. Chemical Science.
11(31), 8301-8305.
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Wang, H., Liu, C., Song, Z., Yuan, M., Ho, Y. A., Gutierrez, O., & Koh, M. J.
(2020).
Engaging alpha-Fluorocarboxylic Acids Directly in Decarboxylative C-C Bond Formation. 10(7), 4451-4459.
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Yuan, M., Song, Z., Badir, S. O., Molander, G. A., & Gutierrez, O.
(2020).
On the Nature of C(sp3)-C(sp2) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides. Journal of the American Chemical Society.
142(15), 7225-7234.
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Xu, B., Troian-Gautier, L., Dykstra, R., Martin, R. T., Gutierrez, O., & Tambar, U. K.
(2020).
Photocatalyzed Diastereoselective Isomerization of Cinnamyl Chlorides to Cyclopropanes. Journal of the American Chemical Society.
142(13), 6206-6215.
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Liu, L., Lee, W., Yuan, M., Acha, C., Geherty, M. B., Williams, B., & Gutierrez, O.
(2020).
Intra- and intermolecular Fe-catalyzed dicarbofunctionalization of vinyl cyclopropanes. Chemical Science.
11(12), 3146-3151.
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Rotella, M. E., Dyer, R., Hilinski, M. K., & Gutierrez, O.
(2020).
Mechanism of Iminium Salt-Catalyzed C(sp3)-H Amination: Factors Controlling Hydride Transfer versus H-Atom Abstraction. ACS Catalysis.
10(1), 897-906.
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Xiao, S., Lee, W., Chen, F. u., Zavalij, P. Y., Gutierrez, O., & Davis, J. T.
(2020).
Oxidation of 8-thioguanosine gives redox-responsive hydrogels and reveals intermediates in a desulfurization pathway. Chemical Communications.
56(51), 6981-6984.
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Thompson, R. R., Rotella, M. E., Du, P. u., Zhou, X., Fronczek, F. R., Kumar, R., Gutierrez, O., & Lee, S.
(2019).
Siloxide Podand Ligand as a Scaffold for Molybdenum-Catalyzed Alkyne Metathesis and Isolation of a Dynamic Metallatetrahedrane Intermediate. Organometallics.
38(21), 4054-4059.
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Hyun, S., Yuan, M., Maity, A., Gutierrez, O., & Powers, D. C.
(2019).
The Role of lodanyl Radicals as Critical Chain Carriers in Aerobic Hypervalent Iodine Chemistry. Chem.
5(9), 2388-2404.
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Sorlin, A. M., Mixdorf, J. C., Rotella, M. E., Martin, R. T., Gutierrez, O., & Nguyen, H. M.
(2019).
The Role of Trichloroacetimidate To Enable Iridium-Catalyzed Regio- and Enantioselective Allylic Fluorination: A Combined Experimental and Computational Study. Journal of the American Chemical Society.
141(37), 14843-14852.
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Lee, W., Yuan, M., Acha, C., Onwu, A., & Gutierrez, O.
(2019).
Mechanism of nitrones and allenoates cascade reactions for the synthesis of dihydro[1,2-a]indoles. Organic and Biomolecular Chemistry.
17(7), 1767-1772.
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Luo, Y., Gutirrez-Bonet, . ., Matsui, J. K., Rotella, M. E., Dykstra, R., Gutierrez, O., & Molander, G. A.
(2019).
Oxa- and Azabenzonorbornadienes as Electrophilic Partners under Photoredox/Nickel Dual Catalysis. ACS Catalysis.
9(9), 8835-8842.
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Liu, L., Lee, W., Zhou, J., Bandyopadhyay, S., & Gutierrez, O.
(2019).
Radical-clock alpha-halo-esters as mechanistic probes for bisphosphine iron-catalyzed cross-coupling reactions. 75(2), 129-136.
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Sutyak, K. B., Lee, W., Zavalij, P. V., Gutierrez, O., & Davis, J. T.
(2018).
Templating and Catalyzing [2+2] Photocycloaddition in Solution Using a Dynamic GQuadruplex. Angewandte Chemie.
130(52), 17392-17396.
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Gutierrez, O., Hendrick, C. E., & Kozlowski, M. C.
(2018).
Divergent Reactivity in Pd-Catalyzed [3,3]-Sigmatropic Rearrangement of Allyloxy- and Propargyloxyindoles Revealed by Computation and Experiment. Organic Letters.
20(20), 6539-6543.
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Phelan, J. P., Lang, S. B., Compton, J. S., Kelly, C. B., Dykstra, R., Gutierrez, O., & Molander, G. A.
(2018).
Redox-Neutral Photocatalytic Cyclopropanation via Radical/Polar Crossover. Journal of the American Chemical Society.
140(25), 8037-8047.
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Cabrera-Afonso, M. J., Lu, Z., Kelly, C. B., Lang, S. B., Dykstra, R., Gutierrez, O., & Molander, G. A.
(2018).
Engaging sulfinate salts via Ni/photoredox dual catalysis enables facile Csp2 -SO2R coupling. Chemical Science.
9(12), 3186-3191.
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Kim, B., Gutierrez, O., Kozlowski, M. C., & Walsh, P. J.
(2018).
A Simple Procedure for the Synthesis of -Hydroxyallenamides via Homoallenylation of Aldehydes. Advanced Synthesis and Catalysis.
360(7), 1426-1432.
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Liu, L., Lee, W., Yuan, M., & Gutierrez, O.
(2018).
Mechanisms of Bisphosphine Iron-Catalyzed C(SP2)-C(SP3) Cross-Coupling Reactions: Inner-Sphere or Outer-Sphere Arylation?. Comments on Inorganic Chemistry.
38(6), 210-237.
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Matsui, J. K., Gutirrez-Bonet, . ., Rotella, M., Alam, R., Gutierrez, O., & Molander, G. A.
(2018).
Photoredox/Nickel-Catalyzed Single-Electron Tsuji-Trost Reaction: Development and Mechanistic Insights. Angewandte Chemie International Edition.
57(48), 15847-15851.
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Matsui, J. K., GutirrezBonet, . ., Rotella, M., Alam, R., Gutierrez, O., & Molander, G. A.
(2018).
Photoredox/NickelCatalyzed SingleElectron TsujiTrost Reaction: Development and Mechanistic Insights. Angewandte Chemie.
130(48), 16073-16077.
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Sutyak, K. B., Lee, W., Zavalij, P. V., Gutierrez, O., & Davis, J. T.
(2018).
Templating and Catalyzing [2+2] Photocycloaddition in Solution Using a Dynamic G-Quadruplex. Angewandte Chemie International Edition.
57(52), 17146-17150.
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Lee, W., Zhou, J., & Gutierrez, O.
(2017).
Mechanism of Nakamura's Bisphosphine-Iron-Catalyzed Asymmetric C(sp2)-C(sp3) Cross-Coupling Reaction: The Role of Spin in Controlling Arylation Pathways. Journal of the American Chemical Society.
139(45), 16126-16133.
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Zou, Y., Gutierrez, O., Sader, A. C., Patel, N. D., Fandrick, D. R., Busacca, C. A., ... Senanayake, C. H.
(2017).
A Computational Investigation of the Ligand-Controlled Cu-Catalyzed Site-Selective Propargylation and Allenylation of Carbonyl Compounds. Organic Letters.
19(22), 6064-6067.
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Li, X., Ridge, C. D., Mazzola, E. P., Sun, J., Gutierrez, O., Moser, A., ... Chen, P.
(2017).
Application of a computer-assisted structure elucidation program for the structural determination of a new terpenoid aldehyde with an unusual skeleton. Magnetic Resonance in Chemistry.
55(3), 210-213.
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Li, M., Gutierrez, O., Berritt, S., Pascual-Escudero, A., Yeilimen, A., Yang, X., ... Walsh, P. J.
(2017).
Transition-metal-free chemo- and regioselective vinylation of azaallyls. Nature Chemistry.
9(10), 997-1004.
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Mazzola, E. P., Gutierrez, O., Fraenkel, G. A., Chow, A., Doyle, M. P., Mandler, M. D., ... Ridge, C. D.
(2016).
Unusually large scalar coupling between geminal protons in a saturated pyrimidine. Concepts in Magnetic Resonance, Part A.
45A(6), e21424-e21424.
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Desrosiers, J., Wei, X., Gutierrez, O., Savoie, J., Qu, B. o., Zeng, X., ... Senanayake, C. H.
(2016).
Nickel-Catalyzed C-3 Direct Arylation of Pyridinium Ions for the Synthesis of 1-Azafluorenes. Chemical Science.
7(8), 5581-5586.
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Wanner, B., Kreituss, I., Gutierrez, O., Kozlowski, M. C., & Bode, J. W.
(2016).
ChemInform Abstract: Catalytic Kinetic Resolution of Disubstituted Piperidines by Enantioselective Acylation: Synthetic Utility and Mechanistic Insights. ChemInform.
47(5), no-no.
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Patel, A., Chen, Z., Yang, Z., Gutirrez, O., Liu, H., Houk, K. N., & Singleton, D. A.
(2016).
Dynamically Complex [6+4] and [4+2] Cycloadditions in the Biosynthesis of Spinosyn A. Journal of the American Chemical Society.
138(11), 3631-3634.
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Harrison, J. G., Gutierrez, O., Jana, N., Driver, T. G., & Tantillo, D. J.
(2016).
Mechanism of Rh2(II)-Catalyzed Indole Formation: The Catalyst Does Not Control Product Selectivity. Journal of the American Chemical Society.
138(2), 487-490.
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Wei, X., Qu, B. o., Zeng, X., Savoie, J., Fandrick, K. R., Desrosiers, J., ... Senanayake, C. H.
(2016).
Sequential C-H Arylation and Enantioselective Hydrogenation Enables Ideal Asymmetric Entry to the Indenopiperidine Core of an 11-HSD-1 Inhibitor. Journal of the American Chemical Society.
138(47), 15473-15481.
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Wanner, B., Kreituss, I., Gutierrez, O., Kozlowski, M. C., & Bode, J. W.
(2015).
Catalytic Kinetic Resolution of Disubstituted Piperidines by Enantioselective Acylation: Synthetic Utility and Mechanistic Insights. Journal of the American Chemical Society.
137(35), 11491-11497.
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Gutierrez, O., Tellis, J. C., Primer, D. N., Molander, G. A., & Kozlowski, M. C.
(2015).
Nickel-catalyzed cross-coupling of photoredox-generated radicals: uncovering a general manifold for stereoconvergence in nickel-catalyzed cross-couplings. Journal of the American Chemical Society.
137(15), 4896-4899.
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Gutierrez, O., Metil, D., Dwivedi, N., Gudimalla, N., Chandrashekar, E., Dahanukar, V. H., ... Kozlowski, M. C.
(2015).
Practical, asymmetric route to sitagliptin and derivatives: development and origin of diastereoselectivity. Organic Letters.
17(7), 1742-1745.
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Williams, D. R., Atwater, B. A., Bawel, S. A., Ke, P., Gutierrez, O., & Tantillo, D. J.
(2014).
ChemInform Abstract: Stereocontrol in Asymmetric SE Reactions of Substituted ,Unsaturated Aldehydes. ChemInform.
45(26), no-no.
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Chen, M. Z., Gutierrez, O., & Smith, A. B.
(2014).
ThroughBond/ThroughSpace Anion Relay Chemistry Exploiting Vinylepoxides as Bifunctional Linchpins. Angewandte Chemie.
126(5), 1303-1306.
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Raffier, L., Gutierrez, O., Stanton, G. R., Kozlowski, M. C., & Walsh, P. J.
(2014).
Alkenes as Chelating Groups in Diastereoselective Additions of Organometallics to Ketones. Organometallics.
33(19), 5371-5377.
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Allen, S. E., Hsieh, S., Gutierrez, O., Bode, J. W., & Kozlowski, M. C.
(2014).
Concerted amidation of activated esters: reaction path and origins of selectivity in the kinetic resolution of cyclic amines via N-heterocyclic carbenes and hydroxamic acid cocatalyzed acyl transfer. Journal of the American Chemical Society.
136(33), 11783-11791.
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Williams, D. R., Atwater, B. A., Bawel, S. A., Ke, P., Gutierrez, O., & Tantillo, D. J.
(2014).
Stereocontrol in asymmetric S(E)' reactions of -substituted ,-unsaturated aldehydes. Organic Letters.
16(2), 468-471.
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Chen, M. Z., Gutierrez, O., & Smith, A. B.
(2014).
Through-bond/through-space anion relay chemistry exploiting vinylepoxides as bifunctional linchpins. Angewandte Chemie International Edition.
53(5), 1279-1282.
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Gutierrez, O., Harrison, J. G., Felix, R. J., Guzman, F. C., Gagn, M. R., & Tantillo, D. J.
(2013).
Carbonium vs. carbenium ion-like transition state geometries for carbocation cyclization - how strain associated with bridging affects 5-exo vs. 6-endo selectivity. Chemical Science.
4(10), 3894-3898.
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Felix, R. J., Gutierrez, O., Tantillo, D. J., & Gagne, M. R.
(2013).
ChemInform Abstract: Gold(I)Catalyzed Formation of Bicyclo[4.2.0]oct1enes. 44(40), no-no.
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Felix, R. J., Gutierrez, O., Tantillo, D. J., & Gagn, M. R.
(2013).
Gold(I)-catalyzed formation of bicyclo[4.2.0]oct-1-enes. Journal of Organic Chemistry.
78(11), 5685-5690.
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Gutierrez, O., Strick, B. F., Thomson, R. J., & Tantillo, D. J.
(2013).
Mechanism of triflimide-catalyzed [3,3]-sigmatropic rearrangements of N-allylhydrazones-predictions and experimental validation. Chemical Science.
4(10), 3997-4003.
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Dickstein, J. S., Curto, J. M., Gutierrez, O., Mulrooney, C. A., & Kozlowski, M. C.
(2013).
Mild aromatic palladium-catalyzed protodecarboxylation: kinetic assessment of the decarboxylative palladation and the protodepalladation steps. Journal of Organic Chemistry.
78(10), 4744-4761.
-
Liu, R., Gutierrez, O., Tantillo, D. J., & Aube, J.
(2012).
ChemInform Abstract: Stereocontrol in a Combined Allylic Azide Rearrangement and Intramolecular Schmidt Reaction. 43(37), no-no.
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Gutierrez, O., & Tantillo, D. J.
(2012).
Analogies between synthetic and biosynthetic reactions in which [1,2]-alkyl shifts are combined with other events: dyotropic, Schmidt, and carbocation rearrangements. Journal of Organic Chemistry.
77(20), 8845-8850.
-
Laulh, S., Bogdanov, B., Johannes, L. M., Gutierrez, O., Harrison, J. G., Tantillo, D. J., Zhang, X., & Nantz, M. H.
(2012).
Fragmentation of oxime and silyl oxime ether odd-electron positive ions by the McLafferty rearrangement: new insights on structural factors that promote , fragmentation. Journal of Mass Spectrometry.
47(6), 676-686.
-
Gutierrez, O., Aub, J., & Tantillo, D. J.
(2012).
Mechanism of the acid-promoted intramolecular schmidt reaction: theoretical assessment of the importance of lone pair-cation, cation-, and steric effects in controlling regioselectivity. Journal of Organic Chemistry.
77(1), 640-647.
-
Gutierrez, O., Harrison, J. G., Pemberton, R. P., & Tantillo, D. J.
(2012).
Re-examining the mechanisms of competing pericyclic reactions of 1,3,7-octatriene. Chemistry - A European Journal.
18(35), 11029-11035.
-
Liu, R., Gutierrez, O., Tantillo, D. J., & Aub, J.
(2012).
Stereocontrol in a combined allylic azide rearrangement and intramolecular Schmidt reaction. Journal of the American Chemical Society.
134(15), 6528-6531.
-
Gutierrez, O., & Tantillo, D. J.
(2010).
Transition Metal Intervention for a Classic Reaction: Assessing the Feasibility of Nickel(0)-Promoted [1,3] Sigmatropic Shifts of Bicyclo[3.2.0]hept-2-enes. Organometallics.
29(16), 3541-3545.
-
Um, J. M., Gutierrez, O., Schoenebeck, F., Houk, K. N., & MacMillan, D.
(2010).
Nature of intermediates in organo-SOMO catalysis of alpha-arylation of aldehydes. Journal of the American Chemical Society.
132(17), 6001-6005.
-
Jung, M. E., Zhang, T., Lui, R. M., Gutierrez, O., & Houk, K. N.
(2010).
Synthesis of a trans,syn,trans-dodecahydrophenanthrene via a bicyclic transannular Diels-Alder reaction: intermediate for the synthesis of fusidic acid. Journal of Organic Chemistry.
75(20), 6933-6940.
-
Gutierrez, O., Iafe, R. G., & Houk, K. N.
(2009).
Origin of stereoselectivity in the imidazolidinone-catalyzed reductions of cyclic alpha,beta-unsaturated ketones. Organic Letters.
11(19), 4298-4301.
-
Wu, D., Martin, R. T., Pia, J., Kwon, J., Crockett, M. P., Thomas, A. A., ... Campos, L. M.
CyclopropenimineMediated CO2 Activation for the Synthesis of Polyurethanes and SmallMolecule Carbonates and Carbamates. Angewandte Chemie.
-
Sar, D., Yin, S., Grygus, J., Rentera-Gmez, . ., Garcia, M., & Gutierrez, O.
Expanding Chemical Space of Enol Silyl Ethers: Catalytic Dicarbofunctionalization Enabled by Iron Catalysis. Chemical Science.
-
Andreetta, P., Martin, R. T., Souilah, C., RenteraGmez, . ., Song, Z., Bayat, Y. K., ... Casitas, A.
Experimental and Computational Studies on Cobalt(I)Catalyzed Regioselective Allylic Alkylation Reactions. Angewandte Chemie.
-
Masson-Makdissi, J., Lalisse, R. F., Yuan, M., Dherange, B. D., Gutierrez, O., & Levin, M. D.
(2024).
Evidence for Dearomatizing Spirocyclization and Dynamic Effects in the Quasi-stereospecific Nitrogen Deletion of Tetrahydroisoquinolines. Journal of the American Chemical Society.
-
chapter
-
Gutierrez, O., & Kozlowski, M. C.
(2014).
Computational Studies on Sigmatropic Rearrangements via Activation by Palladium and Gold Catalysts. Understanding Organometallic Reaction Mechanisms and Catalysis.
(pp. 93-120).
Wiley.
-
Gutierrez, O., & Kozlowski, M. C.
(2014).
Computational Studies on Sigmatropic Rearrangements via Activation by Palladium and Gold Catalysts. Understanding Organometallic Reaction Mechanisms and Catalysis.
(pp. 93-120).
Wiley.
-
conference paper
-
Gutierrez, O.
(2019).
Combining theory and experiment to develop sustainable strategies for C-C bond formation. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
-
Gutierrez, O.
(2019).
Mechanistic studies of asymmetric Fe-catalyzed cross -coupling reactions as a platform for reaction discovery. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
-
Escalante, N., Villa, J., de la Rosa, I., Gutierrez, O., & Rodriguez-Vera, R.
(2013).
Curvelet Transform Method for Phase-Map Denoising. 133-143.
-
Felix, R. J., Weber, D., Gutierrez, O., Tantillo, D. J., & Gagn, M. R.
(2012).
A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes. Nature Chemistry.
405-409.
-
Liu, R., Gutierrez, O., Tantillo, D. J., & Aube, J.
(2012).
Combined allylic azide rearrangement and intramolecular Schmidt reaction. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
-
Um, J. M., Gutierrez, O., Schoenebeck, F., Houk, K. N., & MacMillan, D.
(2010).
Nature of intermediates in organo-SOMO catalysis of a-arylation of aldehydes. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
-
Gutierrez, O.
(2019).
Combining theory and experiment to develop sustainable strategies for C-C bond formation. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
-
institutional repository document
-
Youshaw, C., Yang, M., Achyut, G., Rentera-Gmez, A., Liu, L., Morehead, L., & Gutierrez, O.
(2023).
Iron-Catalyzed Enantioselective Multicomponent Cross-Couplings of alpha-Boryl Radicals
-
Youshaw, C., Yang, M., Achyut, G., Rentera-Gmez, A., Liu, L., Morehead, L., & Gutierrez, O.
(2023).
Iron-Catalyzed Enantioselective Multicomponent Cross-Couplings of alpha-Boryl Radicals
-
Rentera-Gmez, . ., Guerrero, M., Ramirez-Lopez, M., & gutierrez, o.
(2023).
Regioselective Fluoroalkylarylation of Enamides Enabled by an Iron-Catalyzed Multicomponent Radical Cross-Coupling Strategy
-
Scheidt, K., Peng, Q., Gutierrez, O., Gogoi, A., & Rentera-Gmez, A.
(2022).
Visible Light-Induced Coupling of Carboxylic Acids with Alcohols and Amines
-
Scheidt, K., Gutierrez, O., Zhu, J., Tam, A., Renteria-Gomez, A., & Gogoi, A.
(2022).
Photoinduced Acylations Via Azolium-Promoted Intermolecular Hydrogen Atom Transfer
-
Rentera-Gmez, A., Lee, W., Yin, S., Davis, M., Gogoi, A., & Gutierrez, O.
(2022).
General and Practical Route to Diverse 1,3-(Difluoro)alkyl bicyclo[1.1.1]-Aryl Pentanes Enabled by an Fe-Catalyzed Multicomponent Radical Coupling
-
Liu, L., Lee, W., Youshaw, C. R., Yuan, M., Geherty, M. B., Zavalij, P. Y., & Gutierrez, O.
(2020).
Fe-Catalyzed Conjunctive Cross-Couplings of Unactivated Alkenes with Grignard Reagents
-
Liu, L., Lee, W., Youshaw, C. R., Yuan, M., Geherty, M. B., Zavalij, P. Y., & Gutierrez, O.
(2020).
Fe-Catalyzed Conjunctive Cross-Couplings of Unactivated Alkenes with Grignard Reagents
-
Liu, L., Lee, W., Youshaw, C. R., Yuan, M., Geherty, M. B., Zavalij, P. Y., & Gutierrez, O.
(2020).
Fe-Catalyzed Conjunctive Cross-Couplings of Unactivated Alkenes with Grignard Reagents
-
Liu, L., Lee, W., Yuan, M., Acha, C., Geherty, M. B., Williams, B., & Gutierrez, O.
(2019).
Design and Development of Fe-Catalyzed Intra- and Intermolecular Carbofunctionalization of Vinyl Cyclopropanes
-
Liu, L., Lee, W., Yuan, M., Acha, C., Geherty, M. B., Williams, B., & Gutierrez, O.
(2019).
Design and Development of Fe-Catalyzed Intra- and Intermolecular Carbofunctionalization of Vinyl Cyclopropanes
-
Youshaw, C., Yang, M., Achyut, G., Rentera-Gmez, A., Liu, L., Morehead, L., & Gutierrez, O.
(2023).
Iron-Catalyzed Enantioselective Multicomponent Cross-Couplings of alpha-Boryl Radicals
Teaching
teaching activities
- CHEM120 Fund Of Chemistry Ii Instructor
- CHEM228 Organic Chemistry Ii Instructor
- CHEM446 Organic Chemistry Iii Instructor
- CHEM491 Hnr-research Instructor
- CHEM646 Physical Organic Chem Instructor
- CHEM685 Directed Studies Instructor
- CHEM691 Research Instructor
Contact
first name
- Osvaldo
has last name
- Gutierrez Santacruz
Other
- og.labs@tamu.edu