selected publications academicarticle Sun, P. B., Pomfret, M. N., Elardo, M. J., Suresh, A., Rentera-Gmez, . ., Lalisse, R. F., ... Golder, M. R. (2024). Molecular Ball Joints: Mechanochemical Perturbation of Bullvalene Hardy-Cope Rearrangements in Polymer Networks. Journal of the American Chemical Society. 146(28), 19229-19238. Masson-Makdissi, J., Lalisse, R. F., Yuan, M., Dherange, B. D., Gutierrez, O., & Levin, M. D. (2024). Evidence for Dearomatizing Spirocyclization and Dynamic Effects in the Quasi-stereospecific Nitrogen Deletion of Tetrahydroisoquinolines. Journal of the American Chemical Society. Targos, K., Gogoi, A. R., ngel Rentera-Gmez, .., Kim, M. J., Gutierrez, O., & Wickens, Z. K. (2024). Mechanism of Z-Selective Allylic Functionalization via Thianthrenium Salts. Journal of the American Chemical Society. Laskar, R., Dutta, S., Spies, J. C., Mukherjee, P., Rentera-Gmez, . ., Thielemann, R. E., ... Glorius, F. (2024). -Amino Alcohols via Energy Transfer Enabled Brook Rearrangement. Journal of the American Chemical Society. Wu, D., Martin, R. T., Pia, J., Kwon, J., Crockett, M. P., Thomas, A. A., ... Campos, L. M. (2024). Cyclopropenimine-Mediated CO2 Activation for the Synthesis of Polyurethanes and Small-Molecule Carbonates and Carbamates. Angewandte Chemie International Edition. e202401281. Mandal, H., Ogunyemi, O. J., Nicholson, J. L., Orr, M. E., Lalisse, R. F., Rentera-Gmez, . ., ... Goodson, T. (2024). Linear and Nonlinear Optical Properties of All-cis and All-trans Poly(p-phenylenevinylene). Journal of Physical Chemistry C. 128(6), 2518-2528. Alvarez, E. M., Stewart, G., Ullah, M., Lalisse, R., Gutierrez, O., & Malapit, C. A. (2024). Site-Selective Electrochemical Arene C-H Amination. Journal of the American Chemical Society. Wu, F., Chintawar, C. C., Lalisse, R., Mukherjee, P., Dutta, S., Tyler, J., ... Glorius, F. (2024). Ring expansion of indene by photoredox-enabled functionalized carbon-atom insertion. Nature Catalysis. Youshaw, C. R., Yang, M., Gogoi, A. R., Rentera-Gmez, A., Liu, L., Morehead, L. M., & Gutierrez, O. (2023). Iron-Catalyzed Enantioselective Multicomponent Cross-Couplings of -Boryl Radicals. Organic Letters. 25(46), 8320-8325. Yang, Y., Tsien, J., Dykstra, R., Chen, S., Wang, J. B., Merchant, R. R., ... Qin, T. (2023). Programmable late-stage functionalization of bridge-substituted bicyclo[1.1.1]pentane bis-boronates. Nature Chemistry. Andreetta, P., Martin, R. T., Souilah, C., Rentera-Gmez, . ., Song, Z., Khorramshahi Bayat, Y., ... Casitas, A. (2023). Experimental and Computational Studies on Cobalt(I)-Catalyzed Regioselective Allylic Alkylation Reactions. Angewandte Chemie International Edition. e202310129. Rentera-Gmez, . ., Guerrero, M., Ramirez-Lopez, M., & Gutierrez, O. (2023). Regioselective Fluoroalkylarylation of Enamides Enabled by an Iron-Catalyzed Multicomponent Radical Cross-Coupling Strategy. Organic Letters. Aguilera, M. C., Gogoi, A. R., Lee, W., Liu, L., Brennessel, W. W., Gutierrez, O., & Neidig, M. L. (2023). Insight into Radical Initiation, Solvent Effects, and Biphenyl Production in Iron-Bisphosphine Cross-Couplings. ACS Catalysis. 13(13), 8987-8996. Crockett, M. P., Pia, J., Gogoi, A. R., Lalisse, R. F., Nguyen, A. V., Gutierrez, O., & Thomas, A. A. (2023). Breaking the tert-Butyllithium Contact Ion Pair: A Gateway to Alternate Selectivity in Lithiation Reactions. Journal of the American Chemical Society. 145(19), 10743-10755. Peng, Q., Gogoi, A. R., Rentera-Gmez, . ., Gutierrez, O., & Scheidt, K. A. (2023). Visible light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy. Chem. Zhou, M., Tsien, J., Dykstra, R., Hughes, J., Peters, B. K., Merchant, R. R., Gutierrez, O., & Qin, T. (2023). Alkyl sulfinates as cross-coupling partners for programmable and stereospecific installation of C(sp3) bioisosteres. Nature Chemistry. 15(4), 550-559. Day, C., Renteria-Gomez, A., Ton, S., Gogoi, A. R., Gutierrez, O., & Martin, R. (2023). Elucidating electron-transfer events in polypyridine nickel complexes for reductive coupling reactions. Nature Catalysis. 6(3), 244-253. Matsuo, B., Majhi, J., Granados, A., Sharique, M., Martin, R. T., Gutierrez, O., & Molander, G. A. (2023). Transition metal-free photochemical C-F activation for the preparation of difluorinated-oxindole derivatives. Chemical Science. 14(9), 2379-2385. Berger, K. J., Driscoll, J. L., Yuan, M., Dherange, B. D., Gutierrez, O., & Levin, M. D. (2023). Addition to "Direct Deamination of Primary Amines via Isodiazene Intermediates". Journal of the American Chemical Society. 145(1), 745-745. Dherange, B. D., Yuan, M., Kelly, C. B., Reiher, C. A., Grosanu, C., Berger, K. J., Gutierrez, O., & Levin, M. D. (2023). Direct Deaminative Functionalization. Journal of the American Chemical Society. 145(1), 17-24. Zhu, J. L., Schull, C. R., Tam, A. T., Rentera-Gmez, . ., Gogoi, A. R., Gutierrez, O., & Scheidt, K. A. (2023). Photoinduced Acylations Via Azolium-Promoted Intermolecular Hydrogen Atom Transfer. Journal of the American Chemical Society. 145(3), 1535-1541. Li, X., Yuan, M., Chen, F., Huang, Z., Qing, F., Gutierrez, O., & Chu, L. (2023). Three-component enantioselective alkenylation of organophosphonates via nickel metallaphotoredox catalysis. Chem. 9(1), 154-169. Dhungana, R. K., Granados, A., Ciccone, V., Martin, R. T., Majhi, J., Sharique, M., Gutierrez, O., & Molander, G. A. (2022). Trifunctionalization of Cinnamyl Alcohols Provides Access to Brominated alpha,alpha-Difluoro-gamma-lactones via a Photoinduced Radical-Polar-Radical Mechanism. ACS Catalysis. 12(24), 15750-15757. Tan, G., Paulus, F., Rentera-Gmez, . ., Lalisse, R. F., Daniliuc, C. G., Gutierrez, O., & Glorius, F. (2022). Highly Selective Radical Relay 1,4-Oxyimination of Two Electronically Differentiated Olefins. Journal of the American Chemical Society. 144(47), 21664-21673. Renteria-Gomez, A., Lee, W., Yin, S., Davis, M., Gogoi, A. R., & Gutierrez, O. (2022). General and Practical Route to Diverse 1-(Difluoro)alkyl-3-aryl Bicyclo[1.1.1]pentanes Enabled by an Fe-Catalyzed Multicomponent Radical Cross-Coupling Reaction. 12(19), 11547-11556. Majhi, J., Dhungana, R. K., Rentera-Gmez, . ., Sharique, M., Li, L., Dong, W., Gutierrez, O., & Molander, G. A. (2022). Metal-Free Photochemical Imino-Alkylation of Alkenes with Bifunctional Oxime Esters. Journal of the American Chemical Society. 144(34), 15871-15878. Wen, Y., Rentera-Gmez, . ., Day, G. S., Smith, M. F., Yan, T., Ozdemir, R., ... Zhou, H. (2022). Integrated Photocatalytic Reduction and Oxidation of Perfluorooctanoic Acid by Metal-Organic Frameworks: Key Insights into the Degradation Mechanisms. 144(26), 11840-11850. Yuan, M., & Gutierrez, O. (2022). Mechanisms, Challenges, and Opportunities of Dual Ni/Photoredox-Catalyzed C(sp2)-C(sp3) Cross-Couplings. 12(3), e1573. Wang, H., Liu, C., Martin, R. T., Gutierrez, O., & Koh, M. J. (2022). Author Correction: Directing-group-free catalytic dicarbofunctionalization of unactivated alkenes. Nature Chemistry. 14(2), 239-239. Altundas, B., Alwedi, E., Song, Z., Gogoi, A. R., Dykstra, R., Gutierrez, O., & Fleming, F. F. (2022). Dearomatization of aromatic asmic isocyanides to complex cyclohexadienes. Nature Communications. 13(1), 6444. Wang, H., Liu, C., Martin, R. T., Gutierrez, O., & Koh, M. J. (2022). Directing-group-free catalytic dicarbofunctionalization of unactivated alkenes. Nature Chemistry. 14(2), 188-195. Rotella, M. E., Sar, D., Liu, L., & Gutierrez, O. (2021). Fe-Catalyzed dicarbofunctionalization of electron-rich alkenes with Grignard reagents and (fluoro)alkyl halides. Chemical Communications. 57(93), 12508-12511. Berger, K. J., Driscoll, J. L., Yuan, M., Dherange, B. D., Gutierrez, O., & Levin, M. D. (2021). Direct Deamination of Primary Amines via Isodiazene Intermediates. Journal of the American Chemical Society. 143(42), 17366-17373. Liu, L., Aguilera, M. C., Lee, W., Youshaw, C. R., Neidig, M. L., & Gutierrez, O. (2021). General method for iron-catalyzed multicomponent radical cascades-cross-couplings. Science. 374(6566), 432-439. DeMuth, J. C., Song, Z., Carpenter, S. H., Boddie, T. E., Radovi, A., Baker, T. M., Gutierrez, O., & Neidig, M. L. (2021). Experimental and computational studies of the mechanism of iron-catalysed C-H activation/functionalisation with allyl electrophiles. Chemical Science. 12(27), 9398-9407. Thompson, R. R., Rotella, M. E., Zhou, X., Fronczek, F. R., Gutierrez, O., & Lee, S. (2021). Impact of Ligands and Metals on the Formation of Metallacyclic Intermediates and a Nontraditional Mechanism for Group VI Alkyne Metathesis Catalysts. Journal of the American Chemical Society. 143(24), 9026-9039. Agrawal, T., Martin, R. T., Collins, S., Wilhelm, Z., Edwards, M. D., Gutierrez, O., & Sieber, J. D. (2021). Access to Chiral Diamine Derivatives through Stereoselective Cu-Catalyzed Reductive Coupling of Imines and Allenamides. Journal of Organic Chemistry. 86(7), 5026-5046. Campbell, M. W., Yuan, M., Polites, V. C., Gutierrez, O., & Molander, G. A. (2021). Photochemical C-H Activation Enables Nickel-Catalyzed Olefin Dicarbofunctionalization. Journal of the American Chemical Society. 143(10), 3901-3910. Lipp, A., Badir, S. O., Dykstra, R., Gutierrez, O., & Molander, G. A. (2021). Catalyst-Free Decarbonylative Trifluoromethylthiolation Enabled by Electron Donor-Acceptor Complex Photoactivation. Advanced Synthesis and Catalysis. 363(14), 3507-3520. Liu, C., Wang, H., Martin, R. T., Zhao, H., Gutierrez, O., & Koh, M. J. (2021). Olefin Functionalization/Isomerization Enables Stereoselective Alkene Synthesis. Nature Catalysis. 4(8), 674-683. Guo, L., Yuan, M., Zhang, Y., Wang, F., Zhu, S., Gutierrez, O., & Chu, L. (2020). General Method for Enantioselective Three-Component Carboarylation of Alkenes Enabled by Visible-Light Dual Photoredox/Nickel Catalysis. Journal of the American Chemical Society. 142(48), 20390-20399. Liu, L., Lee, W., Youshaw, C. R., Yuan, M., Geherty, M. B., Zavalij, P. Y., & Gutierrez, O. (2020). Fe-catalyzed three-component dicarbofunctionalization of unactivated alkenes with alkyl halides and Grignard reagents. Chemical Science. 11(31), 8301-8305. Wang, H., Liu, C., Song, Z., Yuan, M., Ho, Y. A., Gutierrez, O., & Koh, M. J. (2020). Engaging alpha-Fluorocarboxylic Acids Directly in Decarboxylative C-C Bond Formation. 10(7), 4451-4459. Yuan, M., Song, Z., Badir, S. O., Molander, G. A., & Gutierrez, O. (2020). On the Nature of C(sp3)-C(sp2) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides. Journal of the American Chemical Society. 142(15), 7225-7234. Xu, B., Troian-Gautier, L., Dykstra, R., Martin, R. T., Gutierrez, O., & Tambar, U. K. (2020). Photocatalyzed Diastereoselective Isomerization of Cinnamyl Chlorides to Cyclopropanes. Journal of the American Chemical Society. 142(13), 6206-6215. Liu, L., Lee, W., Yuan, M., Acha, C., Geherty, M. B., Williams, B., & Gutierrez, O. (2020). Intra- and intermolecular Fe-catalyzed dicarbofunctionalization of vinyl cyclopropanes. Chemical Science. 11(12), 3146-3151. Rotella, M. E., Dyer, R., Hilinski, M. K., & Gutierrez, O. (2020). Mechanism of Iminium Salt-Catalyzed C(sp3)-H Amination: Factors Controlling Hydride Transfer versus H-Atom Abstraction. ACS Catalysis. 10(1), 897-906. Xiao, S., Lee, W., Chen, F. u., Zavalij, P. Y., Gutierrez, O., & Davis, J. T. (2020). Oxidation of 8-thioguanosine gives redox-responsive hydrogels and reveals intermediates in a desulfurization pathway. Chemical Communications. 56(51), 6981-6984. Thompson, R. R., Rotella, M. E., Du, P. u., Zhou, X., Fronczek, F. R., Kumar, R., Gutierrez, O., & Lee, S. (2019). Siloxide Podand Ligand as a Scaffold for Molybdenum-Catalyzed Alkyne Metathesis and Isolation of a Dynamic Metallatetrahedrane Intermediate. Organometallics. 38(21), 4054-4059. Hyun, S., Yuan, M., Maity, A., Gutierrez, O., & Powers, D. C. (2019). The Role of lodanyl Radicals as Critical Chain Carriers in Aerobic Hypervalent Iodine Chemistry. Chem. 5(9), 2388-2404. Sorlin, A. M., Mixdorf, J. C., Rotella, M. E., Martin, R. T., Gutierrez, O., & Nguyen, H. M. (2019). The Role of Trichloroacetimidate To Enable Iridium-Catalyzed Regio- and Enantioselective Allylic Fluorination: A Combined Experimental and Computational Study. Journal of the American Chemical Society. 141(37), 14843-14852. Lee, W., Yuan, M., Acha, C., Onwu, A., & Gutierrez, O. (2019). Mechanism of nitrones and allenoates cascade reactions for the synthesis of dihydro[1,2-a]indoles. Organic and Biomolecular Chemistry. 17(7), 1767-1772. Luo, Y., Gutirrez-Bonet, . ., Matsui, J. K., Rotella, M. E., Dykstra, R., Gutierrez, O., & Molander, G. A. (2019). Oxa- and Azabenzonorbornadienes as Electrophilic Partners under Photoredox/Nickel Dual Catalysis. ACS Catalysis. 9(9), 8835-8842. Liu, L., Lee, W., Zhou, J., Bandyopadhyay, S., & Gutierrez, O. (2019). Radical-clock alpha-halo-esters as mechanistic probes for bisphosphine iron-catalyzed cross-coupling reactions. 75(2), 129-136. Sutyak, K. B., Lee, W., Zavalij, P. V., Gutierrez, O., & Davis, J. T. (2018). Templating and Catalyzing [2+2] Photocycloaddition in Solution Using a Dynamic GQuadruplex. Angewandte Chemie. 130(52), 17392-17396. Gutierrez, O., Hendrick, C. E., & Kozlowski, M. C. (2018). Divergent Reactivity in Pd-Catalyzed [3,3]-Sigmatropic Rearrangement of Allyloxy- and Propargyloxyindoles Revealed by Computation and Experiment. Organic Letters. 20(20), 6539-6543. Phelan, J. P., Lang, S. B., Compton, J. S., Kelly, C. B., Dykstra, R., Gutierrez, O., & Molander, G. A. (2018). Redox-Neutral Photocatalytic Cyclopropanation via Radical/Polar Crossover. Journal of the American Chemical Society. 140(25), 8037-8047. Cabrera-Afonso, M. J., Lu, Z., Kelly, C. B., Lang, S. B., Dykstra, R., Gutierrez, O., & Molander, G. A. (2018). Engaging sulfinate salts via Ni/photoredox dual catalysis enables facile Csp2 -SO2R coupling. Chemical Science. 9(12), 3186-3191. Kim, B., Gutierrez, O., Kozlowski, M. C., & Walsh, P. J. (2018). A Simple Procedure for the Synthesis of -Hydroxyallenamides via Homoallenylation of Aldehydes. Advanced Synthesis and Catalysis. 360(7), 1426-1432. Liu, L., Lee, W., Yuan, M., & Gutierrez, O. (2018). Mechanisms of Bisphosphine Iron-Catalyzed C(SP2)-C(SP3) Cross-Coupling Reactions: Inner-Sphere or Outer-Sphere Arylation?. Comments on Inorganic Chemistry. 38(6), 210-237. Matsui, J. K., Gutirrez-Bonet, . ., Rotella, M., Alam, R., Gutierrez, O., & Molander, G. A. (2018). Photoredox/Nickel-Catalyzed Single-Electron Tsuji-Trost Reaction: Development and Mechanistic Insights. Angewandte Chemie International Edition. 57(48), 15847-15851. Matsui, J. K., GutirrezBonet, . ., Rotella, M., Alam, R., Gutierrez, O., & Molander, G. A. (2018). Photoredox/NickelCatalyzed SingleElectron TsujiTrost Reaction: Development and Mechanistic Insights. Angewandte Chemie. 130(48), 16073-16077. Sutyak, K. B., Lee, W., Zavalij, P. V., Gutierrez, O., & Davis, J. T. (2018). Templating and Catalyzing [2+2] Photocycloaddition in Solution Using a Dynamic G-Quadruplex. Angewandte Chemie International Edition. 57(52), 17146-17150. Lee, W., Zhou, J., & Gutierrez, O. (2017). Mechanism of Nakamura's Bisphosphine-Iron-Catalyzed Asymmetric C(sp2)-C(sp3) Cross-Coupling Reaction: The Role of Spin in Controlling Arylation Pathways. Journal of the American Chemical Society. 139(45), 16126-16133. Zou, Y., Gutierrez, O., Sader, A. C., Patel, N. D., Fandrick, D. R., Busacca, C. A., ... Senanayake, C. H. (2017). A Computational Investigation of the Ligand-Controlled Cu-Catalyzed Site-Selective Propargylation and Allenylation of Carbonyl Compounds. Organic Letters. 19(22), 6064-6067. Li, X., Ridge, C. D., Mazzola, E. P., Sun, J., Gutierrez, O., Moser, A., ... Chen, P. (2017). Application of a computer-assisted structure elucidation program for the structural determination of a new terpenoid aldehyde with an unusual skeleton. Magnetic Resonance in Chemistry. 55(3), 210-213. Li, M., Gutierrez, O., Berritt, S., Pascual-Escudero, A., Yeilimen, A., Yang, X., ... Walsh, P. J. (2017). Transition-metal-free chemo- and regioselective vinylation of azaallyls. Nature Chemistry. 9(10), 997-1004. Mazzola, E. P., Gutierrez, O., Fraenkel, G. A., Chow, A., Doyle, M. P., Mandler, M. D., ... Ridge, C. D. (2016). Unusually large scalar coupling between geminal protons in a saturated pyrimidine. Concepts in Magnetic Resonance, Part A. 45A(6), e21424-e21424. Desrosiers, J., Wei, X., Gutierrez, O., Savoie, J., Qu, B. o., Zeng, X., ... Senanayake, C. H. (2016). Nickel-Catalyzed C-3 Direct Arylation of Pyridinium Ions for the Synthesis of 1-Azafluorenes. Chemical Science. 7(8), 5581-5586. Wanner, B., Kreituss, I., Gutierrez, O., Kozlowski, M. C., & Bode, J. W. (2016). ChemInform Abstract: Catalytic Kinetic Resolution of Disubstituted Piperidines by Enantioselective Acylation: Synthetic Utility and Mechanistic Insights. ChemInform. 47(5), no-no. Patel, A., Chen, Z., Yang, Z., Gutirrez, O., Liu, H., Houk, K. N., & Singleton, D. A. (2016). Dynamically Complex [6+4] and [4+2] Cycloadditions in the Biosynthesis of Spinosyn A. Journal of the American Chemical Society. 138(11), 3631-3634. Harrison, J. G., Gutierrez, O., Jana, N., Driver, T. G., & Tantillo, D. J. (2016). Mechanism of Rh2(II)-Catalyzed Indole Formation: The Catalyst Does Not Control Product Selectivity. Journal of the American Chemical Society. 138(2), 487-490. Wei, X., Qu, B. o., Zeng, X., Savoie, J., Fandrick, K. R., Desrosiers, J., ... Senanayake, C. H. (2016). Sequential C-H Arylation and Enantioselective Hydrogenation Enables Ideal Asymmetric Entry to the Indenopiperidine Core of an 11-HSD-1 Inhibitor. Journal of the American Chemical Society. 138(47), 15473-15481. Wanner, B., Kreituss, I., Gutierrez, O., Kozlowski, M. C., & Bode, J. W. (2015). Catalytic Kinetic Resolution of Disubstituted Piperidines by Enantioselective Acylation: Synthetic Utility and Mechanistic Insights. Journal of the American Chemical Society. 137(35), 11491-11497. Gutierrez, O., Tellis, J. C., Primer, D. N., Molander, G. A., & Kozlowski, M. C. (2015). Nickel-catalyzed cross-coupling of photoredox-generated radicals: uncovering a general manifold for stereoconvergence in nickel-catalyzed cross-couplings. Journal of the American Chemical Society. 137(15), 4896-4899. Gutierrez, O., Metil, D., Dwivedi, N., Gudimalla, N., Chandrashekar, E., Dahanukar, V. H., ... Kozlowski, M. C. (2015). Practical, asymmetric route to sitagliptin and derivatives: development and origin of diastereoselectivity. Organic Letters. 17(7), 1742-1745. Williams, D. R., Atwater, B. A., Bawel, S. A., Ke, P., Gutierrez, O., & Tantillo, D. J. (2014). ChemInform Abstract: Stereocontrol in Asymmetric SE Reactions of Substituted ,Unsaturated Aldehydes. ChemInform. 45(26), no-no. Chen, M. Z., Gutierrez, O., & Smith, A. B. (2014). ThroughBond/ThroughSpace Anion Relay Chemistry Exploiting Vinylepoxides as Bifunctional Linchpins. Angewandte Chemie. 126(5), 1303-1306. Raffier, L., Gutierrez, O., Stanton, G. R., Kozlowski, M. C., & Walsh, P. J. (2014). Alkenes as Chelating Groups in Diastereoselective Additions of Organometallics to Ketones. Organometallics. 33(19), 5371-5377. Allen, S. E., Hsieh, S., Gutierrez, O., Bode, J. W., & Kozlowski, M. C. (2014). Concerted amidation of activated esters: reaction path and origins of selectivity in the kinetic resolution of cyclic amines via N-heterocyclic carbenes and hydroxamic acid cocatalyzed acyl transfer. Journal of the American Chemical Society. 136(33), 11783-11791. Williams, D. R., Atwater, B. A., Bawel, S. A., Ke, P., Gutierrez, O., & Tantillo, D. J. (2014). Stereocontrol in asymmetric S(E)' reactions of -substituted ,-unsaturated aldehydes. Organic Letters. 16(2), 468-471. Chen, M. Z., Gutierrez, O., & Smith, A. B. (2014). Through-bond/through-space anion relay chemistry exploiting vinylepoxides as bifunctional linchpins. Angewandte Chemie International Edition. 53(5), 1279-1282. Gutierrez, O., Harrison, J. G., Felix, R. J., Guzman, F. C., Gagn, M. R., & Tantillo, D. J. (2013). Carbonium vs. carbenium ion-like transition state geometries for carbocation cyclization - how strain associated with bridging affects 5-exo vs. 6-endo selectivity. Chemical Science. 4(10), 3894-3898. Felix, R. J., Gutierrez, O., Tantillo, D. J., & Gagne, M. R. (2013). ChemInform Abstract: Gold(I)Catalyzed Formation of Bicyclo[4.2.0]oct1enes. 44(40), no-no. Felix, R. J., Gutierrez, O., Tantillo, D. J., & Gagn, M. R. (2013). Gold(I)-catalyzed formation of bicyclo[4.2.0]oct-1-enes. Journal of Organic Chemistry. 78(11), 5685-5690. Gutierrez, O., Strick, B. F., Thomson, R. J., & Tantillo, D. J. (2013). Mechanism of triflimide-catalyzed [3,3]-sigmatropic rearrangements of N-allylhydrazones-predictions and experimental validation. Chemical Science. 4(10), 3997-4003. Dickstein, J. S., Curto, J. M., Gutierrez, O., Mulrooney, C. A., & Kozlowski, M. C. (2013). Mild aromatic palladium-catalyzed protodecarboxylation: kinetic assessment of the decarboxylative palladation and the protodepalladation steps. Journal of Organic Chemistry. 78(10), 4744-4761. Liu, R., Gutierrez, O., Tantillo, D. J., & Aube, J. (2012). ChemInform Abstract: Stereocontrol in a Combined Allylic Azide Rearrangement and Intramolecular Schmidt Reaction. 43(37), no-no. Gutierrez, O., & Tantillo, D. J. (2012). Analogies between synthetic and biosynthetic reactions in which [1,2]-alkyl shifts are combined with other events: dyotropic, Schmidt, and carbocation rearrangements. Journal of Organic Chemistry. 77(20), 8845-8850. Laulh, S., Bogdanov, B., Johannes, L. M., Gutierrez, O., Harrison, J. G., Tantillo, D. J., Zhang, X., & Nantz, M. H. (2012). Fragmentation of oxime and silyl oxime ether odd-electron positive ions by the McLafferty rearrangement: new insights on structural factors that promote , fragmentation. Journal of Mass Spectrometry. 47(6), 676-686. Gutierrez, O., Aub, J., & Tantillo, D. J. (2012). Mechanism of the acid-promoted intramolecular schmidt reaction: theoretical assessment of the importance of lone pair-cation, cation-, and steric effects in controlling regioselectivity. Journal of Organic Chemistry. 77(1), 640-647. Gutierrez, O., Harrison, J. G., Pemberton, R. P., & Tantillo, D. J. (2012). Re-examining the mechanisms of competing pericyclic reactions of 1,3,7-octatriene. Chemistry - A European Journal. 18(35), 11029-11035. Liu, R., Gutierrez, O., Tantillo, D. J., & Aub, J. (2012). Stereocontrol in a combined allylic azide rearrangement and intramolecular Schmidt reaction. Journal of the American Chemical Society. 134(15), 6528-6531. Gutierrez, O., & Tantillo, D. J. (2010). Transition Metal Intervention for a Classic Reaction: Assessing the Feasibility of Nickel(0)-Promoted [1,3] Sigmatropic Shifts of Bicyclo[3.2.0]hept-2-enes. Organometallics. 29(16), 3541-3545. Um, J. M., Gutierrez, O., Schoenebeck, F., Houk, K. N., & MacMillan, D. (2010). Nature of intermediates in organo-SOMO catalysis of alpha-arylation of aldehydes. Journal of the American Chemical Society. 132(17), 6001-6005. Jung, M. E., Zhang, T., Lui, R. M., Gutierrez, O., & Houk, K. N. (2010). Synthesis of a trans,syn,trans-dodecahydrophenanthrene via a bicyclic transannular Diels-Alder reaction: intermediate for the synthesis of fusidic acid. Journal of Organic Chemistry. 75(20), 6933-6940. Gutierrez, O., Iafe, R. G., & Houk, K. N. (2009). Origin of stereoselectivity in the imidazolidinone-catalyzed reductions of cyclic alpha,beta-unsaturated ketones. Organic Letters. 11(19), 4298-4301. Wu, D., Martin, R. T., Pia, J., Kwon, J., Crockett, M. P., Thomas, A. A., ... Campos, L. M. CyclopropenimineMediated CO2 Activation for the Synthesis of Polyurethanes and SmallMolecule Carbonates and Carbamates. Angewandte Chemie. Sar, D., Yin, S., Grygus, J., Rentera-Gmez, . ., Garcia, M., & Gutierrez, O. Expanding Chemical Space of Enol Silyl Ethers: Catalytic Dicarbofunctionalization Enabled by Iron Catalysis. Chemical Science. Andreetta, P., Martin, R. T., Souilah, C., RenteraGmez, . ., Song, Z., Bayat, Y. K., ... Casitas, A. Experimental and Computational Studies on Cobalt(I)Catalyzed Regioselective Allylic Alkylation Reactions. Angewandte Chemie. Guerrero, M., Rentera-Gmez, . ., Das, D., & Gutierrez, O. Fe-Catalyzed Fluoroalkyl(hetero)arylation of Vinyl Azaarenes: Rapid and Modular Synthesis of Unsymmetrical 1,1-Bis(hetero)arylalkanes. Organic Letters. Wu, F., Lenz, M., Suresh, A., Gogoi, A. R., Tyler, J. L., Daniliuc, C. G., Gutierrez, O., & Glorius, F. Nitrogen-to-functionalized carbon atom transmutation of pyridine. Chemical Science. Thompson, R. R., Figgins, M. T., Wannipurage, D. C., Renteria-Gomez, A., Gogoi, A. R., Telser, J., ... Powers, D. C. P-P Coupling with and without Terminal Metal-Phosphorus Intermediates. Journal of the American Chemical Society. Peng, Q., Hwang, M. U., Rentera-Gmez, . ., Mukherjee, P., Young, R. M., Qiu, Y., ... Scheidt, K. A. Photochemical phosphorus-enabled scaffold remodeling of carboxylic acids. Science. 385(6716), 1471-1477. Maity, T., Rentera-Gmez, . ., & Gutierrez, O. Stereoselective Fe-Catalyzed Decoupled Cross-Couplings: Chiral Vinyl Oxazolidinones as Effective Radical Lynchpins for Diastereoselective C(sp2)-C(sp3) Bond Formation. ACS Catalysis. 14(17), 13049-13054. chapter Gutierrez, O., & Kozlowski, M. C. (2014). Computational Studies on Sigmatropic Rearrangements via Activation by Palladium and Gold Catalysts. Understanding Organometallic Reaction Mechanisms and Catalysis. (pp. 93-120). Wiley. conference paper Gutierrez, O. (2019). Combining theory and experiment to develop sustainable strategies for C-C bond formation. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. Gutierrez, O. (2019). Mechanistic studies of asymmetric Fe-catalyzed cross -coupling reactions as a platform for reaction discovery. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. Escalante, N., Villa, J., de la Rosa, I., Gutierrez, O., & Rodriguez-Vera, R. (2013). Curvelet Transform Method for Phase-Map Denoising. 133-143. Felix, R. J., Weber, D., Gutierrez, O., Tantillo, D. J., & Gagn, M. R. (2012). A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes. Nature Chemistry. 405-409. Liu, R., Gutierrez, O., Tantillo, D. J., & Aube, J. (2012). Combined allylic azide rearrangement and intramolecular Schmidt reaction. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. Um, J. M., Gutierrez, O., Schoenebeck, F., Houk, K. N., & MacMillan, D. (2010). Nature of intermediates in organo-SOMO catalysis of a-arylation of aldehydes. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. institutional repository document Youshaw, C., Yang, M., Achyut, G., Rentera-Gmez, A., Liu, L., Morehead, L., & Gutierrez, O. (2023). Iron-Catalyzed Enantioselective Multicomponent Cross-Couplings of alpha-Boryl Radicals Youshaw, C., Yang, M., Achyut, G., Rentera-Gmez, A., Liu, L., Morehead, L., & Gutierrez, O. (2023). Iron-Catalyzed Enantioselective Multicomponent Cross-Couplings of alpha-Boryl Radicals Rentera-Gmez, . ., Guerrero, M., Ramirez-Lopez, M., & gutierrez, o. (2023). Regioselective Fluoroalkylarylation of Enamides Enabled by an Iron-Catalyzed Multicomponent Radical Cross-Coupling Strategy Scheidt, K., Peng, Q., Gutierrez, O., Gogoi, A., & Rentera-Gmez, A. (2022). Visible Light-Induced Coupling of Carboxylic Acids with Alcohols and Amines Scheidt, K., Gutierrez, O., Zhu, J., Tam, A., Renteria-Gomez, A., & Gogoi, A. (2022). Photoinduced Acylations Via Azolium-Promoted Intermolecular Hydrogen Atom Transfer Rentera-Gmez, A., Lee, W., Yin, S., Davis, M., Gogoi, A., & Gutierrez, O. (2022). General and Practical Route to Diverse 1,3-(Difluoro)alkyl bicyclo[1.1.1]-Aryl Pentanes Enabled by an Fe-Catalyzed Multicomponent Radical Coupling Liu, L., Lee, W., Youshaw, C. R., Yuan, M., Geherty, M. B., Zavalij, P. Y., & Gutierrez, O. (2020). Fe-Catalyzed Conjunctive Cross-Couplings of Unactivated Alkenes with Grignard Reagents Liu, L., Lee, W., Youshaw, C. R., Yuan, M., Geherty, M. B., Zavalij, P. Y., & Gutierrez, O. (2020). Fe-Catalyzed Conjunctive Cross-Couplings of Unactivated Alkenes with Grignard Reagents Liu, L., Lee, W., Youshaw, C. R., Yuan, M., Geherty, M. B., Zavalij, P. Y., & Gutierrez, O. (2020). Fe-Catalyzed Conjunctive Cross-Couplings of Unactivated Alkenes with Grignard Reagents Liu, L., Lee, W., Yuan, M., Acha, C., Geherty, M. B., Williams, B., & Gutierrez, O. (2019). Design and Development of Fe-Catalyzed Intra- and Intermolecular Carbofunctionalization of Vinyl Cyclopropanes Liu, L., Lee, W., Yuan, M., Acha, C., Geherty, M. B., Williams, B., & Gutierrez, O. (2019). Design and Development of Fe-Catalyzed Intra- and Intermolecular Carbofunctionalization of Vinyl Cyclopropanes
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