Analogies between synthetic and biosynthetic reactions in which [1,2]-alkyl shifts are combined with other events: dyotropic, Schmidt, and carbocation rearrangements. Academic Article

abstract

• A survey of computational studies on the mechanisms of dyotropic, Schmidt, and related reactions is presented. Connections between synthetically applied versions of these processes and those predicted to occur during biosynthetic terpene-forming carbocation cascades are highlighted.

authors

• Gutierrez Santacruz, Osvaldo

published proceedings

• J Org Chem

altmetric score

• 5.168

author list (cited authors)

• Gutierrez, O., & Tantillo, D. J.

citation count

• 49

complete list of authors

• Gutierrez, Osvaldo||Tantillo, Dean J

publication date

• January 2012

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of Organic Chemistry  Journal

keywords

• Molecular Conformation
• Terpenes

PubMed Central ID

• 23006240

Digital Object Identifier (DOI)

• 10.1021/jo301864h

start page

• 8845

end page

• 8850

volume

• 77

issue

• 20

URL

• http://dx.doi.org/10.1021/jo301864h