A new supramolecular bonding motif involving NH bonds of ammonium salts and macrocycles derived from platinum corners and butadiynediyl linkers. Academic Article

abstract

• CuI catalyzes reactions of cis-(R2C(CH2PPh2)2)Pt(CCCCH)2 and cis-(R2C(CH2PPh2)2)PtI2 in secondary amine solvents HNR'2 to give the title adducts [(R2C(CH2PPh2)2)Pt(CCCC)]4(H2NR'2+I-)n (R/R'/n = Me/Et/1, Me/((CH2CH2)2O)0.5/3, Et/Et/1, Et/CH2CHCH2/1; 92-42%). Crystal structures of these or closely related species establish folded Pt4 cores containing ammonium cation guests, with NH/ and NCH/CC hydrogen bonding. DOSY NMR experiments show that the host/guest relationship can be maintained in solution.

authors

• Gladysz, John

published proceedings

• Dalton Trans

author list (cited authors)

• Collins, B. K., Bhuvanesh, N., & Gladysz, J. A.

citation count

• 1

complete list of authors

• Collins, Brenna K||Bhuvanesh, Nattamai||Gladysz, John A

publication date

• November 2022

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• Dalton Transactions  Journal

PubMed Central ID

• 36269068

Digital Object Identifier (DOI)

• 10.1039/d2dt02680e

start page

• 16795

end page

• 16799

volume

• 51

issue

• 44

URL

• http://dx.doi.org/10.1039/d2dt02680e