Fluoroacrylate-bound fluorous-phase soluble hydrogenation catalysts. Academic Article uri icon


  • [reaction: see text] Fluoroacrylate polymer-bound hydrogenation catalysts are described. N-Acryloxysuccinimide-containing fluoroacrylate polymers were converted into phosphine ligands and subsequently into analogues of Wilkinson's catalyst by amidation of N-acryloxysuccinimide active ester residues and Rh exchange. The resulting catalysts have excellent activity and can be reused following fluorous biphasic liquid/liquid separation and extraction.

published proceedings

  • Org Lett

altmetric score

  • 3

author list (cited authors)

  • Bergbreiter, D. E., Franchina, J. G., & Case, B. L.

citation count

  • 45

complete list of authors

  • Bergbreiter, DE||Franchina, JG||Case, BL

publication date

  • February 2000