Applications of catalysts on soluble supports. Academic Article

abstract

• The use of soluble polymers as supports for catalysts is discussed and reviewed. Strategies where immobilized catalysts on soluble polymers are used in a monophasic reaction, but where the immobilized catalyst is recovered as an insoluble polymer-supported species in a liquid/solid separation step, are discussed. Such strategies include temperature perturbation, pH perturbation, and solvent precipitation as a means of producing a solid/liquid mixture for separation after a homogeneous reaction. Strategies where immobilized catalysts on soluble polymers are used in a monophasic reaction, but where the immobilized catalyst is recovered in one phase of a biphasic liquid/liquid mixture, are also described. Examples where temperature perturbation or additive addition are used as a means of producing a solid/liquid mixture for separation after a homogeneous reaction are discussed. Finally, examples where soluble polymers are used as supports homogeneously or biphasically and separated from products by membrane filtration or biphasic extraction are described.

authors

• Bergbreiter, David

published proceedings

• Top Curr Chem

author list (cited authors)

• Bergbreiter, D. E.

citation count

• 33

complete list of authors

• Bergbreiter, David E

publication date

• January 2004

publisher

• Springer Nature  Publisher

published in

• Topics in Current Chemistry  Journal

keywords

• Biphasic Catalysis
• Catalysis Separation
• Latent Biphasic
• Soluble Polymers
• Thermomorphic

Digital Object Identifier (DOI)

• 10.1007/b96875

start page

• 113

end page

• 176

volume

• 242

URL

• http://dx.doi.org/10.1007/b96875