Structural, physical, and chemical properties of fluorous compounds.

abstract

• The sizes and structures of fluorous molecules are analyzed, particularly with respect to the helical conformations of perfluoroalkyl segments and their phase separation in crystal lattices. Basic molecular properties, bond energies, and special bonding motifs are reviewed. Solubility, adsorption, and related phenomena are treated. Miscibilities of fluorous solvents, and partition coefficients of solutes in fluorous/organic biphase mixtures, are analyzed. Electronic effects and NMR properties are discussed, and some reactions involving the fluorinated parts of fluorous substances are presented.

authors

• Gladysz, John

published proceedings

• Top Curr Chem

altmetric score

• 6.25

author list (cited authors)

• Gladysz, J. A., & Jurisch, M.

citation count

• 43

complete list of authors

• Gladysz, John A||Jurisch, Markus

publication date

• January 2012

publisher

• Springer Nature  Publisher

published in

• Topics in Current Chemistry  Journal

keywords

• Bond Energies
• Conformations
• Electronic Effects
• Fluorous
• Miscibilities
• NMR
• Partition Coefficient
• Reactivity
• Solubilities

PubMed Central ID

• 21972027

Digital Object Identifier (DOI)

• 10.1007/128_2011_282

start page

• 1

end page

• 23

volume

• 308

URL

• https://doi.org/10.1007/128_2011_282