Anomalous size effects in nanoporous materials induced by high surface energies Academic Article uri icon


  • Copyright © Materials Research Society 2019. Several experiments and molecular dynamics calculations have reported anomalous mechanical behaviors of nanoporous materials that may be attributed to capillary effects. For example, nanoporous gold exhibits a tension-compression asymmetry in yield strength with the material being stronger in compression than tension. In addition, some molecular dynamics calculations have reported a spontaneous collapse of pores in nanoporous gold with nanometer-sized ligaments. Despite these perplexing observations, there are few theoretical models capable of shedding light on such capillary phenomena, particularly under general stress states. Here, we utilize a physics-based model to explore the implications of high surface energies on the mechanical response of dislocation-starved nanoporous materials subject to general stress states. For low stress triaxialities, we report an anomalous size effect and an anomalous temperature-dependence of dislocation-starved nanoporous materials with sufficiently large surface energies. Additionally, we provide an analytic criterion for spontaneous pore collapse in nanoporous materials with nanometer-sized ligaments.

author list (cited authors)

  • Wilkerson, J. W.

citation count

  • 1

publication date

  • January 1, 2019 11:11 AM


  • Nanoscale
  • Nanostructure
  • Strength