Substitution mechanisms at metal carbonyl centers; conversion of Ph3P(CO)4ReBr to Ph3P(CO)4ReCH3 via an anionic acyl intermediate Academic Article uri icon


  • The substitution reaction Ph3P(CO)4ReBr + CH3Li → Ph3P(CO)4ReCH3 is shown to occur by initial CH3Li attack upon coordinated CO. © 1980, All rights reserved.

author list (cited authors)

  • W. Parker, D., Marsi, M., & Gladysz, J. A.

citation count

  • 17

publication date

  • January 1980