Substitution mechanisms at metal carbonyl centers; conversion of Ph3P(CO)4ReBr to Ph3P(CO)4ReCH3 via an anionic acyl intermediate

abstract

• The substitution reaction Ph3P(CO)4ReBr + CH3Li Ph3P(CO)4ReCH3 is shown to occur by initial CH3Li attack upon coordinated CO. 1980, All rights reserved.

authors

• Gladysz, John

published proceedings

• Journal of Organometallic Chemistry

author list (cited authors)

• W. Parker, D., Marsi, M., & Gladysz, J. A.

citation count

• 18

complete list of authors

• W. Parker, David||Marsi, Marianne||Gladysz, JA

publication date

• July 1980

publisher

• Elsevier BV  Publisher

published in

• Journal of Organometallic Chemistry  Journal

Digital Object Identifier (DOI)

• 10.1016/s0022-328x(00)90345-0

start page

• C1

end page

• C4

volume

• 194

issue

• 1

URL

• https://doi.org/10.1016/s0022-328x(00)90345-0