Substitution mechanisms at metal carbonyl centers; conversion of Ph3P(CO)4ReBr to Ph3P(CO)4ReCH3 via an anionic acyl intermediate Academic Article uri icon


  • The substitution reaction Ph3P(CO)4ReBr + CH3Li Ph3P(CO)4ReCH3 is shown to occur by initial CH3Li attack upon coordinated CO. 1980, All rights reserved.

published proceedings

  • Journal of Organometallic Chemistry

author list (cited authors)

  • W. Parker, D., Marsi, M., & Gladysz, J. A.

citation count

  • 18

complete list of authors

  • W. Parker, David||Marsi, Marianne||Gladysz, JA

publication date

  • July 1980