Preparation, gas chromatographic behavior, and spectroscopic properties of hydroxylated chlorobiphenyls. Academic Article

abstract

• Abstract Some useful methods for the preparation of chlorobiphenylols have been investigated. Twenty monohydroxy and dihydroxy derivatives of chlorobiphenyls are described; 10 are new compounds and several are known metabolic products from animals or microorganisms. The relationship between structure of the chlorobiphenylols and gas chromatographic retention time as well as electron capture detector response, including those of derivatives, has been examined. The ultraviolet, fluorescence, and mass spectra of these hydroxylated derivatives have also been examined with a view towards analysis and structure elucidation of metabolites.

authors

• Safe, Stephen

published proceedings

• J Assoc Off Anal Chem

author list (cited authors)

• Hutzinger, O., Safe, S., & Zitko, V.

citation count

• 29

complete list of authors

• Hutzinger, O||Safe, S||Zitko, V

publication date

• September 1974

publisher

• Oxford University Press (OUP)  Publisher

published in

• Journal - Association of Official Analytical Chemists  Journal

keywords

• Chromatography, Gas
• Chromatography, Thin Layer
• Hydroxylation
• Mass Spectrometry
• Methods
• Polychlorinated Biphenyls
• Spectrometry, Fluorescence
• Spectrophotometry, Ultraviolet
• Structure-Activity Relationship

PubMed Central ID

• 4213308

Digital Object Identifier (DOI)

• 10.1093/jaoac/57.5.1061

start page

• 1061

end page

• 1067

volume

• 57

issue

• 5

URL

• http://dx.doi.org/10.1093/jaoac/57.5.1061