Luminescence of Molecular Nitrogen Nanoclusters Containing Stabilized Atoms. Academic Article

abstract

• We studied the luminescence of molecular nitrogen nanoclusters containing stabilized nitrogen, oxygen, hydrogen, and deuterium atoms. Optical spectra were observed during the destruction of these ensembles of nanoclusters accompanied by a rapid release of chemical energy stored in the samples. Several interesting features were observed including a broad band near 360 nm, which was identified as emission corresponding to 2Ag1Ag transition of N4(D2h) polymeric nitrogen. Also the sharp lines at 336 and 473 nm were observed, and their assignments to ND radicals are discussed.

authors

• Khmelenko, Vladimir
• Lee, David

published proceedings

• J Phys Chem A

altmetric score

• 0.25

author list (cited authors)

• McColgan, P. T., Meraki, A., Boltnev, R. E., Lee, D. M., & Khmelenko, V. V.

citation count

• 6

complete list of authors

• McColgan, Patrick T||Meraki, Adil||Boltnev, Roman E||Lee, David M||Khmelenko, Vladimir V

publication date

• November 2017

publisher

• American Chemical Society (ACS)  Publisher

published in

• The Journal of Physical Chemistry A: Isolated Molecules, Clusters, Radicals, and Ions; Environmental Chemistry, Geochemistry, and Astrochemistry; Theory  Journal

keywords

• 0306 Physical Chemistry (incl. Structural)

PubMed Central ID

• 29112821

Digital Object Identifier (DOI)

• 10.1021/acs.jpca.7b09661

start page

• 9045

end page

• 9057

volume

• 121

issue

• 47

URL

• http://dx.doi.org/10.1021/acs.jpca.7b09661