FACILE SEPARATIONS OF ENANTIOMERS OF CHIRAL ORGANOMETALLIC COMPOUNDS WITH A BAKERBOND CHIRALCEL HPLC COLUMN
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Enantiomers of 22 compounds of the formula (6-C5R5)M(L)(PAr3)(X) (M/L = Re/NO, Fe/CO) are separated under the title conditions (hexane/2-propanol). In each case, theoretical plate numbers, capacity factors, separation factors, and resolution are determined. Trends in these data and compounds for which enantiomers are not resolved are discussed. 1991, American Chemical Society. All rights reserved.