Facile separations of enantiomers of chiral organometallic compounds with a Bakerbond Chiralcel HPLC column Academic Article uri icon


  • Enantiomers of 22 compounds of the formula (η6-C5R5)M(L)(PAr3)(X) (M/L = Re/NO, Fe/CO) are separated under the title conditions (hexane/2-propanol). In each case, theoretical plate numbers, capacity factors, separation factors, and resolution are determined. Trends in these data and compounds for which enantiomers are not resolved are discussed. © 1991, American Chemical Society. All rights reserved.

author list (cited authors)

  • Ramsden, J. A., Garner, C. M., & Gladysz, J. A.

citation count

  • 25

publication date

  • May 1991