A short, unsupported Cu(I)Cu(I) interaction, 2.65 Å, in a dinuclear guanidine chloride complex Academic Article uri icon

abstract

  • The reaction of CuCl with the neutral guanidine Hhpp ligand (1,3,4,6,7,8-hexahydropyrimido[1,2-a]pyrimidine) yields two crystalline polymorphs of the neutral dimer, bis(1,3,4,6,7,8-hexahydropyrimido[1,2-a]pyrimidine) dichloro-di-copper(I) with the shortest distance known for a bridging unsupported copper(I)-copper(I) interaction.

author list (cited authors)

  • Chiarella, G. M., Melgarejo, D. Y., Rozanski, A., Hempte, P., Perez, L. M., Reber, C., & Fackler, J. P.

citation count

  • 43

publication date

  • January 2010