Analysis of chlorinated aromatic hydrocarbons by exhaustive chlorination: qualitative and structural aspects of the perchloro-derivatives of biphenyl, naphthalene, terphenyl, dibenzofuran, dibenzodioxin and DDE.
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abstract
A number of reagents for the exhaustive chlorination of aromatic compounds were in- vestigated. Antimony pentachloride-iodine, and the BMC reagent (sulfuryl chloride- aluminum chloride-disulfur dichloride) were found to be the most effective and convenient reagents. They are liquids which can be used without special precautions to prepare the perchloro-derivatives of biphenyl, terphenyl, naphthalene, dibenzofuran, dibenzodioxin and DDE. The structures, mass spectra and GLC properties of these compounds are discussed. 1972, Taylor & Francis Group, LLC. All rights reserved.