A NEW CATALYST FOR THE EPIMERIZATION OF SECONDARY ALCOHOLS - CARBON HYDROGEN-BOND ACTIVATION IN THE RHENIUM ALKOXIDE COMPLEXES (ETA-5-C5R5)RE(NO)(PPH3)(OCHRR') Academic Article uri icon

abstract

  • The methoxide complexes (5-C5R5)Re(NO)-(PPh3KOCH3) (R = H, Me) catalyze the title reaction (65-90 C, C6H5R solvent); intermediate secondary alkoxide complexes undergo PPh3 dissociation and sequential epimerization at rhenium and carbon. 1991, American Chemical Society. All rights reserved.

published proceedings

  • ORGANOMETALLICS

author list (cited authors)

  • SAURALLAMAS, I., GARNER, C. M., & GLADYSZ, J. A.

citation count

  • 6

complete list of authors

  • SAURALLAMAS, I||GARNER, CM||GLADYSZ, JA

publication date

  • August 1991