A NEW CATALYST FOR THE EPIMERIZATION OF SECONDARY ALCOHOLS - CARBON HYDROGEN-BOND ACTIVATION IN THE RHENIUM ALKOXIDE COMPLEXES (ETA-5-C5R5)RE(NO)(PPH3)(OCHRR')

abstract

• The methoxide complexes (5-C5R5)Re(NO)-(PPh3KOCH3) (R = H, Me) catalyze the title reaction (65-90 C, C6H5R solvent); intermediate secondary alkoxide complexes undergo PPh3 dissociation and sequential epimerization at rhenium and carbon. 1991, American Chemical Society. All rights reserved.

authors

• Gladysz, John

published proceedings

• ORGANOMETALLICS

author list (cited authors)

• SAURALLAMAS, I., GARNER, C. M., & GLADYSZ, J. A.

citation count

• 6

complete list of authors

• SAURALLAMAS, I||GARNER, CM||GLADYSZ, JA

publication date

• August 1991

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organometallics  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1021/om00054a003

start page

• 2533

end page

• 2535

volume

• 10

issue

• 8

URL

• https://doi.org/10.1021/om00054a003