Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes Academic Article uri icon

abstract

  • The title reaction is applied to square-planar rhodium and platinum complexes with trans PPh2(CH2)6CH=CH2 ligands, and square-planar platinum or octahedral tungsten complexes with trans or facial PPh[(CH2)6CH=CH2]2 ligands. Ring-closing (poly)macrocyclizations occur.

author list (cited authors)

  • Bauer, E. B., Ruwwe, J., Martín-Alvarez, J. M., Peters, T. B., Bohling, J. C., Hampel, F. A., ... Gladysz, J. A.

citation count

  • 50

publication date

  • January 2000