Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes
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abstract
The title reaction is applied to square-planar rhodium and platinum complexes with trans PPh2(CH2)6CH=CH2 ligands, and square-planar platinum or octahedral tungsten complexes with trans or facial PPh[(CH2)6CH=CH2]2 ligands. Ring-closing (poly)macrocyclizations occur.