"Click" Chemistry in Metal Coordination Spheres: Copper(I)-Catalyzed 3+2 Cycloadditions of Benzyl Azide and Platinum Polyynyl Complexes trans-(C6F5)(p-tol(3)P)(2)Pt(C C)(n)H (n=2-6)
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Summary; Benzyl azide and the terminal polyynyl complexes trans-(C 6F5)(p-tol3P)2Pt(CC) nH(n = 2-6) undergo 3+2 "click" cycloadditions in the presence of CuSO4/ascorbic acid to give the 1,2,3-triazoles trans-(C6 F5)(p-tol3P)2Pt(CC) n-1 C=CHN(CH2C6H5)N=N, four of which are structurally characterized. 2009 American Chemical Society.