Regiospecific, diastereospecific and enantiospecific nucleophilic additions to chiral monosubstituted alkene complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(H2CCHR)]+ BF4−
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Monosubstituted alkene complexes [(η5-C5H5)Re(NO)(PPh3)(H2CCHR)]+ BF4- and (CH3)2 CuLi react to give β-branched alkyl complexes (η5-C5H5)Re(NO)(PPh3)(CH2CH(CH3)R) as described in the title. The methyl group adds to the alkene face anti to the rhenium. © 1990.
author list (cited authors)
Peng, T., & Gladysz, J. A.