REGIOSPECIFIC, DIASTEREOSPECIFIC AND ENANTIOSPECIFIC NUCLEOPHILIC ADDITIONS TO CHIRAL MONOSUBSTITUTED ALKENE COMPLEXES OF THE FORMULA [ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+ BF4-
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abstract
Monosubstituted alkene complexes [(5-C5H5)Re(NO)(PPh3)(H2CCHR)]+ BF4- and (CH3)2 CuLi react to give -branched alkyl complexes (5-C5H5)Re(NO)(PPh3)(CH2CH(CH3)R) as described in the title. The methyl group adds to the alkene face anti to the rhenium. 1990.