Deprotonation and anionic rearrangements of organometallic compounds. Reactions of the hydride complex (η 5 -C 5 H 5 )Re(NO)(PPh 3 )(H) with n-butyl-lithium–tetramethylethylenediamine
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The title reaction (-71 °C; 1 h) gives (η5-C 5H4Li)Re(NO)(PPh3)(H) (8), which subsequently rearranges intramolecularly (-32 °C; 0.5 h) to give Li+[(η 5-C5H5)Re(NO)(PPh3)]- (3); the anions (8) and (3) are characterized by reactions with electrophiles.
author list (cited authors)
Crocco, G. L., & Gladysz, J. A.