DEPROTONATION AND ANIONIC REARRANGEMENTS OF ORGANOMETALLIC COMPOUNDS - REACTIONS OF THE HYDRIDE COMPLEX (ETA-5-C5H5)RE(NO)(PPH3)(H) WITH NORMAL-BUTYL-LITHIUM-TETRAMETHYLETHYLENEDIAMINE Academic Article uri icon

abstract

  • The title reaction (-71 C; 1 h) gives (5-C 5H4Li)Re(NO)(PPh3)(H) (8), which subsequently rearranges intramolecularly (-32 C; 0.5 h) to give Li+[( 5-C5H5)Re(NO)(PPh3)]- (3); the anions (8) and (3) are characterized by reactions with electrophiles.

published proceedings

  • JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS

author list (cited authors)

  • CROCCO, G. L., & GLADYSZ, J. A.

citation count

  • 16

complete list of authors

  • CROCCO, GL||GLADYSZ, JA

publication date

  • January 1985