Deprotonation and anionic rearrangements of organometallic compounds. Reactions of the hydride complex (5-C5H5)Re(NO)(PPh3)(H) with n-butyl-lithiumtetramethylethylenediamine
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The title reaction (-71 C; 1 h) gives (5-C 5H4Li)Re(NO)(PPh3)(H) (8), which subsequently rearranges intramolecularly (-32 C; 0.5 h) to give Li+[( 5-C5H5)Re(NO)(PPh3)]- (3); the anions (8) and (3) are characterized by reactions with electrophiles.
J. Chem. Soc., Chem. Commun.
author list (cited authors)
Crocco, G. L., & Gladysz, J. A.
complete list of authors
Crocco, Guy L||Gladysz, JA