REACTIONS OF CHIRAL (ALPHA-METHOXYVINYL)RHENIUM COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(C(OCH3)=CHR) WITH ALKYL-HALIDES - EFFICIENT 1,3-ASYMMETRIC INDUCTION Academic Article uri icon

abstract

  • -Methoxyvinyl complexes (Z)-(5-C5H5)Re-(NO)(PPh3)(C(OCH3)=CHR) are readily alkylated (C6H5CH2Br, CH3I) to give acyl complexes (5-C5H5)Re-(NO)(PPh3)(COCHRR') with high diastereoselectivity; the stereochemistry of these reactions, and probable transition-state geometries, are established by an X-ray crystal structure of the product (SR, RS)-(5-C5H5)Re(NO)-(PPh3)(COCH(CH3)CH2C6H5). 1985, American Chemical Society. All rights reserved.

published proceedings

  • ORGANOMETALLICS

author list (cited authors)

  • SMITH, D. E., & GLADYSZ, J. A.

citation count

  • 11

complete list of authors

  • SMITH, DE||GLADYSZ, JA

publication date

  • August 1985