A NEW CARBON HYDROGEN-BOND ACTIVATION REACTION - STEREOSPECIFIC ABSTRACTION OF VINYLIC PROTONS FROM RHENIUM ALKENE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+BF4-BY THE BASE TERT-BUO-K+ Academic Article uri icon

abstract

  • The title reaction gives the vinyl complexes (5-C5H5)Re(NO)(PPh3(CH=CHR) for R = CH(CH3)2 and C6H5; deuterium labeling and NMR experiments show that only one of the two geminal alkene ligand protons is abstracted.

published proceedings

  • ORGANOMETALLICS

author list (cited authors)

  • PENG, T. S., & GLADYSZ, J. A.

citation count

  • 15

complete list of authors

  • PENG, TS||GLADYSZ, JA

publication date

  • November 1990