INTRODUCTION OF SULFUR INTO ORGANIC-MOLECULES VIA LITHIUM TRIETHYLBOROHYDRIDE REDUCTION OF S-8
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abstract
Solutions in tetrahydrofuran of Li2S and Li2S 2 (or chemically equivalent species) are rapidly formed by reaction of elemental sulphur with appropriate stoicheiometries of LiEt3BH; subsequent addition of electrophiles affords sulphide or disulphide derivatives in high yields.