SYNTHESIS AND DECARBOXYLATION MECHANISM OF THE CHIRAL RHENIUM FORMATE (ETA-C5H5)RE(NO)(PPH3)(OCHO) Academic Article

abstract

• Formate (-C5H5)Re(NO)(PPH3)(OCHO) (1) de-carboxylates to (-C5H5)Re(NO)(PPH3)(H) (2) without PPH3 dissociation, with retention at rhenium, with kH/kD (112 C) = 1.55 0.19, H = 26.8 0.6 kcal/mol, and S = -6.3 1.3 eu. 1983, American Chemical Society. All rights reserved.

authors

• Gladysz, John

published proceedings

• ORGANOMETALLICS

author list (cited authors)

• MERRIFIELD, J. H., & GLADYSZ, J. A.

citation count

• 34

complete list of authors

• MERRIFIELD, JH||GLADYSZ, JA

publication date

• June 1983

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organometallics  Journal

Digital Object Identifier (DOI)

• 10.1021/om00078a022

start page

• 782

end page

• 784

volume

• 2

issue

• 6

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fom00078a022