Pyrrolyl-N and pyrrolyl-C complexes of the chiral rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+: synthesis, protonation, and rearrangement chemistry Academic Article uri icon


  • The pyrrolyl-N complex (η-C5H5)Re(NO)-(PPh3)(NC4H4) and TfOH or HBF4·OEt2react to give 2H-pyrrole complexes [formula omitted] These rearrange to the carbon-ligated species [formula omitted] which is characterized crystallographically and treated with KH to give the pyr-rolyl-C complex [formula omitted]. © 1993, American Chemical Society. All rights reserved.

author list (cited authors)

  • Johnson, T. J., Arif, A. M., & Gladysz, J. A.

citation count

  • 16

publication date

  • December 1993