PYRROLYL-N AND PYRROLYL-C COMPLEXES OF THE CHIRAL RHENIUM FRAGMENT [(ETA(5)-C5H5)RE(NO)(PPH3)]+ - SYNTHESIS, PROTONATION, AND REARRANGEMENT CHEMISTRY Academic Article uri icon

abstract

  • The pyrrolyl-N complex (-C5H5)Re(NO)-(PPh3)(NC4H4) and TfOH or HBF4OEt2react to give 2H-pyrrole complexes [formula omitted] These rearrange to the carbon-ligated species [formula omitted] which is characterized crystallographically and treated with KH to give the pyr-rolyl-C complex [formula omitted]. 1993, American Chemical Society. All rights reserved.

published proceedings

  • ORGANOMETALLICS

author list (cited authors)

  • JOHNSON, T. J., ARIF, A. M., & GLADYSZ, J. A.

citation count

  • 26

complete list of authors

  • JOHNSON, TJ||ARIF, AM||GLADYSZ, JA

publication date

  • December 1993