PYRROLYL-N AND PYRROLYL-C COMPLEXES OF THE CHIRAL RHENIUM FRAGMENT [(ETA(5)-C5H5)RE(NO)(PPH3)]+ - SYNTHESIS, PROTONATION, AND REARRANGEMENT CHEMISTRY

abstract

• The pyrrolyl-N complex (-C5H5)Re(NO)-(PPh3)(NC4H4) and TfOH or HBF4OEt2react to give 2H-pyrrole complexes [formula omitted] These rearrange to the carbon-ligated species [formula omitted] which is characterized crystallographically and treated with KH to give the pyr-rolyl-C complex [formula omitted]. 1993, American Chemical Society. All rights reserved.

authors

• Gladysz, John

published proceedings

• ORGANOMETALLICS

author list (cited authors)

• JOHNSON, T. J., ARIF, A. M., & GLADYSZ, J. A.

citation count

• 26

complete list of authors

• JOHNSON, TJ||ARIF, AM||GLADYSZ, JA

publication date

• December 1993

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organometallics  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1021/om00036a006

start page

• 4728

end page

• 4730

volume

• 12

issue

• 12

URL

• https://doi.org/10.1021/om00036a006