Syntheses and structures of monoplatinum model complexes for diplatinum polyynediyl adducts L_nPt(CC)_zPtL_n Conference Paper

abstract

• The CuI-catalyzed reactions of trans-(Ph3P)2PtCl2 with HCCSiMe3 or HCCCCSiMe3 (greater than two equivalents, HNEt2), and trans-(p-tol)(Ph3P)2PtCl (4) or trans-(C6F5)(p-tol3P)2PtCl with HCCCCH, give trans-(Ph3P)2Pt(CCSiMe3)2 (2), trans-(Ph3P)2Pt(CCCCSiMe3)2 (3), trans-(p-tol)(Ph3P)2PtCCCCH (5), and trans-(C6F5)(p-tol3P)2PtCCCCH (7) in 74-81% yields. These compounds are characterized crystallographically, and their physical properties compared. A convenient three-step synthesis of 4 from (COD)PtCl2 is described. 2002 Elsevier Science B.V. All rights reserved.

authors

• Gladysz, John

published proceedings

• JOURNAL OF ORGANOMETALLIC CHEMISTRY

altmetric score

• 3

author list (cited authors)

• Peters, T. B., Zheng, Q. L., Stahl, J., Bohling, J. C., Arif, A. M., Hampel, F., & Gladysz, J. A.

citation count

• 27

complete list of authors

• Peters, TB||Zheng, QL||Stahl, J||Bohling, JC||Arif, AM||Hampel, F||Gladysz, JA

publication date

• January 2002

publisher

• Elsevier  Publisher

published in

• Journal of Organometallic Chemistry  Journal

keywords

• Alkynyl And Butadiynyl Complexes
• Crystal Structures
• Hagihara Coupling
• Platinum

Digital Object Identifier (DOI)

• 10.1016/S0022-328X(01)01311-0

start page

• 53

end page

• 61

volume

• 641

issue

• 1-2

URL

• https://doi.org/10.1016/s0022-328x(01)01311-0