REACTIONS OF THE TERMINAL RHENIUM ACETYLIDE COMPLEX RE(ETA-5-C5H5)(NO)(PPH3)(CCH) AND BUTYLLITHIUM - GENERATION, ALKYLATION AND STANNYLATION OF LITHIOCARBIDE COMPLEXES OF THE FORMULA RE(ETA-5-C5H4X)(NO)(PPH3)(CCLI) (X = H, LI)
Academic Article
Overview
Research
Identity
Additional Document Info
Other
View All
Overview
abstract
The title reaction gives, depending upon stoichiometry and conditions, Re(5-C5H5)(NO)(PPh3) (CCLi) and Re(5-C5H4Li)(NO) (PPh3)(CCLi); the first transition metal-alkali metal carbide complexes which are in turn derivatized by carbon and metal electrophiles.