REACTIONS OF THE TERMINAL RHENIUM ACETYLIDE COMPLEX RE(ETA-5-C5H5)(NO)(PPH3)(CCH) AND BUTYLLITHIUM - GENERATION, ALKYLATION AND STANNYLATION OF LITHIOCARBIDE COMPLEXES OF THE FORMULA RE(ETA-5-C5H4X)(NO)(PPH3)(CCLI) (X = H, LI) Academic Article uri icon

abstract

  • The title reaction gives, depending upon stoichiometry and conditions, Re(5-C5H5)(NO)(PPh3) (CCLi) and Re(5-C5H4Li)(NO) (PPh3)(CCLi); the first transition metal-alkali metal carbide complexes which are in turn derivatized by carbon and metal electrophiles.

published proceedings

  • JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS

author list (cited authors)

  • RAMSDEN, J. A., AGBOSSOU, F., SENN, D. R., & GLADYSZ, J. A.

complete list of authors

  • RAMSDEN, JA||AGBOSSOU, F||SENN, DR||GLADYSZ, JA