SYNTHESIS AND REACTIVITY OF CHIRAL RHENIUM AMINE AND AMIDE COMPLEXES OF THE FORMULAS [(ETA-5-C5H5)RE(NO)(PPH3)(NHRR')]+TFO- AND (ETA-5-C5H5)RE(NO)(PPH3)(NRR')

abstract

• Reactions of racemic and optically active (5-C5H5)Re(NO)(PPh3)(OTf) with primary and secondary amines give the amine complexes [(5-C5H5)Re(NO)-(PPh3)(NHRR)]+TfO- with retention of configuration at rhenium. These react with n-BuLi to give amide complexes (5-C5H5)Re(NO)(PPh3)(NRR) that contain an unusually basic and nucleophilic nitrogen. 1990, American Chemical Society. All rights reserved.

authors

• Gladysz, John

published proceedings

• ORGANOMETALLICS

author list (cited authors)

• DEWEY, M. A., BAKKE, J. M., & GLADYSZ, J. A.

citation count

• 12

complete list of authors

• DEWEY, MA||BAKKE, JM||GLADYSZ, JA

publication date

• April 1990

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organometallics  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1021/om00118a083

start page

• 1349

end page

• 1351

volume

• 9

issue

• 4

URL

• https://doi.org/10.1021/om00118a083