NEW FAMILIES OF COORDINATED CARBON - OXIDATIVE COUPLING AND CROSS-COUPLING OF A TRANSITION-METAL BUTADIYNYL COMPLEX TO BIMETALLIC M-C-CC-CC-CC-C-M AND M-C-CC-CC-C-M ADDUCTS Academic Article uri icon

abstract

  • [(5-C5Me5)Re(NO)(PPh 3)(CCCCCCCC)(Ph3P)(ON) Re(5-C5Me5)] and [(5- C5Me5)Re(NO)(PPh3)(CCCCCC) -(Ph3P)(ON)Re(5-C5Me5)], which contain the longest chains of elemental carbon tethered between two transition metals to date, are prepared by Cu(OAc)2 coupling of [(5-C5Me5)Re(NO)(PPh3) (CCCCH)], or cross-coupling with the corresponding ethynyl complex; unusual spectroscopic and redox properties are described.

published proceedings

  • JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS

author list (cited authors)

  • BRADY, M., WENG, W. Q., & GLADYSZ, J. A.

citation count

  • 83

complete list of authors

  • BRADY, M||WENG, WQ||GLADYSZ, JA

publication date

  • December 1994