A CRYSTALLOGRAPHIC MAP OF CHIRAL RECOGNITION IN PI-COMPLEXES OF AROMATIC-ALDEHYDES AND A CHIRAL TRANSITION-METAL LEWIS-ACID - ENANTIOFACE BINDING SELECTIVITIES IN SOLUTION CORRELATE TO DISTANCES BETWEEN METAL AND CARBON STEREOCENTERS IN THE SOLID-STATE Academic Article uri icon

abstract

  • The title claim is established with five -aromatic aldehyde complexes [(5-C5H5)Re(NO)(PPh3) (2-O=CHAr)]+ X-; electronegative aryl substituents give shorter rhenium-carbon bond lengths and higher binding selectivities, providing the first easily conceptualized mechanism for an electronic effect upon chiral recognition.

published proceedings

  • JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS

author list (cited authors)

  • BOONE, B. J., KLEIN, D. P., MENDEZ, N. Q., SEYLER, J. W., ARIF, A. M., & GLADYSZ, J. A.

citation count

  • 5

complete list of authors

  • BOONE, BJ||KLEIN, DP||MENDEZ, NQ||SEYLER, JW||ARIF, AM||GLADYSZ, JA

publication date

  • December 1995