π/σ Equilibria in rhenium ketone complexes [(η5-C5H5)Re(NO)(PPh3)(OCRR′)]+X−; a marked electronic effect upon the binding mode
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The first series of metal ketone complexes for which both π and σ isomers can be isolated is reported. Electron-withdrawing substituents favor the π binding mode. © 1991.
author list (cited authors)
Klein, D. P., Dalton, D. M., Méndez, N. Q., Arif, A. M., & Gladysz, J. A.