PI/SIGMA EQUILIBRIA IN RHENIUM KETONE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(O=CRR')]+X- - A MARKED ELECTRONIC EFFECT UPON THE BINDING MODE
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abstract
The first series of metal ketone complexes for which both and isomers can be isolated is reported. Electron-withdrawing substituents favor the binding mode. 1991.