REACTIONS OF DIPHENYL(TRIMETHYLSILYL)PHOSPHANE WITH ALKYL(PENTACARBONYL)MANGANESE - SYNTHESIS OF THE YLIDE COMPLEXES (CO)4MNCR(OSIME3)PPH2 AND A NEW DRIVING FORCE FOR CO INSERTION Academic Article uri icon

abstract

  • Promotion of COinsertion into metalalkyl bonds is of current interest. A novel possibility is provided by the use of the silylphosphane 1: The COinsertion is assisted by formation of the SiO bond. This reaction opens up access to the ylide complexes 3. (Figure Presented.) Copyright 1984 by Verlag Chemie, GmbH, Germany

published proceedings

  • ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH

author list (cited authors)

  • VAUGHN, G. D., KREIN, K. A., & GLADYSZ, J. A.

citation count

  • 8

complete list of authors

  • VAUGHN, GD||KREIN, KA||GLADYSZ, JA

publication date

  • March 1984

publisher