REACTIONS OF DIPHENYL(TRIMETHYLSILYL)PHOSPHANE WITH ALKYL(PENTACARBONYL)MANGANESE - SYNTHESIS OF THE YLIDE COMPLEXES (CO)4MNCR(OSIME3)PPH2 AND A NEW DRIVING FORCE FOR CO INSERTION
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Promotion of COinsertion into metalalkyl bonds is of current interest. A novel possibility is provided by the use of the silylphosphane 1: The COinsertion is assisted by formation of the SiO bond. This reaction opens up access to the ylide complexes 3. (Figure Presented.) Copyright 1984 by Verlag Chemie, GmbH, Germany