Mononuclear anionic formyl complexes; synthesis and properties Academic Article uri icon

abstract

  • A series of kinetically unstable mononuclear anionic formyl complexes have been prepared by the action of Li(C2H5)3BH on neutral metal carbonyl precursors. One of these, Li+[(CO)4Mn(COC6H5)(CHO)]-, is shown to decompose by a hydride transfer disproportionation mechanism involving the by-product (C2H5)3B. © 1981.

author list (cited authors)

  • Selover, J. C., Marsi, M., Parker, D. W., & Gladysz, J. A.

citation count

  • 20

publication date

  • March 1981