Mononuclear anionic formyl complexes; synthesis and properties
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A series of kinetically unstable mononuclear anionic formyl complexes have been prepared by the action of Li(C2H5)3BH on neutral metal carbonyl precursors. One of these, Li+[(CO)4Mn(COC6H5)(CHO)]-, is shown to decompose by a hydride transfer disproportionation mechanism involving the by-product (C2H5)3B. © 1981.
author list (cited authors)
Selover, J. C., Marsi, M., Parker, D. W., & Gladysz, J. A.