MONONUCLEAR ANIONIC FORMYL COMPLEXES - SYNTHESIS AND PROPERTIES uri icon

abstract

  • A series of kinetically unstable mononuclear anionic formyl complexes have been prepared by the action of Li(C2H5)3BH on neutral metal carbonyl precursors. One of these, Li+[(CO)4Mn(COC6H5)(CHO)]-, is shown to decompose by a hydride transfer disproportionation mechanism involving the by-product (C2H5)3B. 1981.

published proceedings

  • JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

  • SELOVER, J. C., MARSI, M., PARKER, D. W., & GLADYSZ, J. A.

citation count

  • 22

complete list of authors

  • SELOVER, JC||MARSI, M||PARKER, DW||GLADYSZ, JA

publication date

  • March 1981