MODIFICATION OF SUBSTRATE REACTIVITY USING SOLUBLE POLYMERIC SUPPORTS Academic Article uri icon

abstract

  • The effects of polymer size and solvent on the reactivity of a soluble polymer-bound substrate in heterogeneous hydrogenation reactions has been examined using PEG polymer ligands. Hydrogenation of a substrate was completely suppressed by virtue of the polymer's size and/or immiscibility with some catalysts. Changing solvents significantly perturbed reactivity of such soluble polymer-bound substrates even using Pt C. 1995.

published proceedings

  • TETRAHEDRON LETTERS

author list (cited authors)

  • BERGBREITER, D. E., KIMMEL, T., & CARAWAY, J. W.

citation count

  • 7

complete list of authors

  • BERGBREITER, DE||KIMMEL, T||CARAWAY, JW

publication date

  • July 1995