POLYETHYLENE CARBOXYLATE-BOUND TRIRUTHENIUM CLUSTERS AS ALCOHOL OXIDATION CATALYSTS
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abstract
We have found that addition of polyethylene oligomers containing a terminal carboxylic acid group to solutions of [(CH3CH2CO2)6Ru3O(H2O)3] +CH3CH2CO2- allows us to recover quantitatively and reuse this ruthenium cluster as a catalyst for oxidation of primary and secondary alcohols with oxygen. 1990.