NUCLEAR MAGNETIC-RESONANCE STUDIES OF METHYLSILVER(I) COMPLEXES Academic Article

abstract

• Methylsilver(I) complexes have been studied by 1H, 7Li, 13C, and 31P NMR spectroscopy, and structural information about the methylsilver(I), lithium dimethylsilver(I), and dilithium trimethylsilver(I) complexes has been obtained. Possible structures of these complexes are discussed in terms of the results of these multinuclear NMR studies. Variable-temperature NMR of these complexes has also been studied. These NMR studies show that intermolecular exchange of methyl groups occuss for each of these complexes. The activation parameters for these exchange processes were determined from line-shape analysis of the dynamic 13C NMR spectra of these complexes. 1983, American Chemical Society. All rights reserved.

authors

• Bergbreiter, David

published proceedings

• ORGANOMETALLICS

author list (cited authors)

• BERGBREITER, D. E., LYNCH, T. J., & SHIMAZU, S.

citation count

• 10

complete list of authors

• BERGBREITER, DE||LYNCH, TJ||SHIMAZU, S

publication date

• October 1983

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organometallics  Journal

Digital Object Identifier (DOI)

• 10.1021/om50004a017

start page

• 1354

end page

• 1359

volume

• 2

issue

• 10

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fom50004a017