Synthesis and characterization of electronically varied XCX palladacycles with functional arene groups Academic Article

abstract

• X-ray crystallographic studies show that varying the nature of the S-aryl ligands in SCS-Pd(II) pincer complexes and the electronic nature of the aryl substituent para to the Pd(II) group in PCP-Pd(II) pincer complexes do not lead to structural changes in these palladacycles that can be correlated with the changing nature of the ligands. While the original C2 symmetry for the S-aryl groups in SCS-Pd(II) pincer complexes seen in the case of the 2,5-bis(thiophenylmethyl)phenylpalladium chloride pincer complex is also seen in other SCS-Pd(II) pincer complexes, the relative stereochemistry of the S-aryl rings is not consistently maintained in 2,5-bis((4-dimethylaminothiophenyl) methyl)-phenylpalladium chloride. 2005 Elsevier B.V. All rights reserved.

authors

• Bergbreiter, David

published proceedings

• INORGANICA CHIMICA ACTA

altmetric score

• 3

author list (cited authors)

• Bergbreiter, D. E., Frels, J. D., Rawson, J., Li, J., & Reibenspies, J. H.

citation count

• 17

complete list of authors

• Bergbreiter, DE||Frels, JD||Rawson, J||Li, J||Reibenspies, JH

publication date

• April 2006

publisher

• Elsevier  Publisher

published in

• Inorganica Chimica Acta  Journal

keywords

• Catalysis
• Palladacycles
• Pincer Complexes
• Structure
• Synthesis

Digital Object Identifier (DOI)

• 10.1016/j.ica.2005.09.030

start page

• 1912

end page

• 1922

volume

• 359

issue

• 6

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2Fj.ica.2005.09.030