Pd-catalyzed synthesis of a tethered soluble polymeric phosphine ligand Academic Article

abstract

• The use of a Pd-catalyzed phosphine-aryl iodide coupling chemistry to prepare soluble polymeric phosphine ligands is described. The lack of sensitivity of the catalyst to the presence of excess phosphine ligand and the fact that the soluble polymeric phosphine ligands are effective ligands for the active catalyst results in a self-replicating ligand synthesis. Ligand or ligand plus catalyst recovery is achieved by solvent precipitation of the polymeric product of this chemistry.

authors

• Bergbreiter, David

published proceedings

• TETRAHEDRON LETTERS

author list (cited authors)

• Bergbreiter, D. E., Liu, Y. S., Furyk, S., & Case, B. L.

citation count

• 19

complete list of authors

• Bergbreiter, DE||Liu, YS||Furyk, S||Case, BL

publication date

• November 1998

publisher

• Elsevier  Publisher

published in

• Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry
• 3405 Organic Chemistry

Digital Object Identifier (DOI)

• 10.1016/S0040-4039(98)01976-5

start page

• 8799

end page

• 8802

volume

• 39

issue

• 48

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2Fs0040-4039%2898%2901976-5