Designing Phase Selectively Soluble Polymer-Supports for Dimethylaminopyridine and Phosphine-Ligated Pd(0) Catalysts Conference Paper

abstract

• 2014 Springer Science+Business Media New York. Soluble poly(4-alkylstyrene) containing 4-methyl-, 4-tert-butyl, 4-dodecyl-, and 4-octadecylstyrene were formed either with monomers containing dyes-, ligands, or catalysts or with 5-10 mol% of 4-chloromethylstyrene and studied as supports for ligands or catalysts. Studies with dye-labeled polymers showed that polymers containing longer alkyl groups alone or at ca. 10 mol% loading are highly soluble in heptane can be used to separate and recycle organo- and transition metal catalysts.

authors

• Bazzi, Hassan Said
• Bergbreiter, David

published proceedings

• TOPICS IN CATALYSIS

author list (cited authors)

• Khamatnurova, T. V., Johnson, M., Santana, D., Bazzi, H. S., & Bergbreiter, D. E.

citation count

• 7

complete list of authors

• Khamatnurova, Tatyana V||Johnson, Mitchel||Santana, David||Bazzi, Hassan S||Bergbreiter, David E

publication date

• November 2014

publisher

• Springer Nature  Publisher

published in

• Topics in Catalysis  Journal

keywords

• Cross Coupling
• Dimethylaminopyridine
• Palladium
• Phosphine
• Recycling
• Suzuki

Digital Object Identifier (DOI)

• 10.1007/s11244-014-0315-3

start page

• 1438

end page

• 1444

volume

• 57

issue

• 17-20

URL

• http%3A%2F%2Fdx.doi.org%2F10.1007%2Fs11244-014-0315-3