ELECTROPHILIC ASYMMETRIC SYNTHESES OF ALPHA-HYDROXY CARBOXYLIC-ACIDS
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abstract
Asymmetric electrophilic synthesis of -hydroxy carboxylic acids from chiral amide derivatives of tert-butyl- and trialkylsilyl- protected glycolic and lactic acids are described which lead to chiral -hydroxy carboxylic acids in 60-95% diastereomic excess. 1986.