HR job title
- Retired Professor and Associate Department Head
- Contact Info
- 1 979 845 0215
Hughbanks, Timothy Professor and Associate Department Head
Positions
- Professor and Associate Department Head, Chemistry, College of Arts and Sciences
Solid state chemists are playing a crucial role in shaping the future of chemistry through the synthesis of new materials with novel properties. We combine the traditional strengths of molecular chemists with those of materials scientists to study interesting materials while training versatile scientists.
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Overview
Publications
selected publications
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academic article
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Escobedo-Cruz, F. V., & Hughbanks, T.
(2018).
New coordination networks containing trinuclear lanthanide complexes and hexacyanometallates. Dalton Transactions.
47(19), 6831-6841.
-
Escobedo-Cruz, F. V., & Hughbanks, T.
(2018).
Synthesis and characterization of a new cubic structure in the reduced zirconium iodide chemistry. Inorganica Chimica Acta.
469, 545-549.
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Kanatzidis, M. G., Poeppelmeier, K. R., Bobev, S., Guloy, A. M., Hwu, S., Lachgar, A., ... Seshadri, R.
(2008).
Report from the third workshop on future directions of solid-state chemistry: The status of solid-state chemistry and its impact in the physical sciences. Progress in Solid State Chemistry.
36(1-2), 1-133.
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Roy, L. E., & Hughbanks, T.
(2007).
Tight binding prediction of the -Gd2S3 magnetic structure. Journal of Solid State Chemistry.
180(3), 818-823.
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Roy, L. E., & Hughbanks, T.
(2006).
A tight-binding method for predicting magnetic ordering in Gd-containing solids: Application to GdB2C2. The Journal of Physical Chemistry B: Biophysical Chemistry, Biomaterials, Liquids, and Soft Matter.
110(41), 20290-20296.
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Roy, L. E., & Hughbanks, T
(2006).
Magnetic coupling in dinuclear Gd complexes. Journal of the American Chemical Society.
128(2), 568-575.
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Sweet, L. E., & Hughbanks, T
(2006).
CsR(R(6)CoI(12))2 (R = Gd, Er) and (CeI)0.26(Ce(6)MnI(9))2: two new structure types featuring R(6)Z clusters. Inorganic Chemistry.
45(24), 9696-9702.
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Roy, L. E., & Hughbanks, T
(2006).
Electronic transitions in [Re6S8X6](4-) (X = Cl, Br, I): results from time-dependent density functional theory and solid-state calculations. Inorganic Chemistry.
45(20), 8273-8282.
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Sweet, L. E., Roy, L. E., Meng, F., & Hughbanks, T
(2006).
Ferromagnetic coupling in hexanuclear gadolinium clusters. Journal of the American Chemical Society.
128(31), 10193-10201.
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Magliocchi, C., Xie, X., & Hughbanks, T
(2004).
Cyanide-melt synthesis of reduced molybdenum selenide clusters. Inorganic Chemistry.
43(6), 1902-1911.
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Magliocchi, C., Meng, F., & Hughbanks, T.
(2004).
Rare-earth-rich tellurides: Gd4NiTe2 and Er5M2Te2 (M=Co, Ni). Journal of Solid State Chemistry.
177(11), 3896-3902.
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Shen, J., & Hughbanks, T.
(2004).
A DFT Study of the Interstitial Chemical Shifts in Main Group Element Centered Hexazirconium Halide Clusters. The Journal of Physical Chemistry A: Isolated Molecules, Clusters, Radicals, and Ions; Environmental Chemistry, Geochemistry, and Astrochemistry; Theory.
108(2), 350-357.
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Tripathi, A., Hughbanks, T., & Clearfield, A.
(2003).
The first framework solid composed of vanadosilicate clusters. Journal of the American Chemical Society.
125(35), 10528-10529.
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Meng, F., Magliocchi, C., & Hughbanks, T.
(2003).
Synthesis, structure and bonding of Gd6MTe2 (M=Co, Ni), Er6RuTe2. Journal of Alloys and Compounds.
358(1-2), 98-103.
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Roy, L., & Hughbanks, T.
(2003).
d-Electron mediated 4f74f7 exchange in Gd-rich compounds; spin density functional study of Gd2Cl3. Journal of Solid State Chemistry.
176(2), 294-305.
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Xie, X., & Hughbanks, T
(2002).
N-centered hexazirconium chloride clusters: excision and redox chemistry. Inorganic Chemistry.
41(7), 1824-1830.
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Kim, J., Byeon, S. H., & Hughbanks, T.
(2002).
Rearrangement of host layers upon the insertion of organic cations: Synthesis and structure of (CH3NH3)MnTe2. CHEMISTRY OF MATERIALS.
14(1), 9-+.
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Xie, X., Jones, J. N., & Hughbanks, T
(2001).
Excision of zirconium iodide clusters from highly cross-linked solids. Inorganic Chemistry.
40(3), 522-527.
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Kim, J., & Hughbanks, T.
(2001).
Direct and indirect preparation of layered quaternary manganese tellurides; AMnxMyTe2 (A=Li, Na; M=Cu, Ag; x+y2). Journal of Alloys and Compounds.
327(1-2), 116-120.
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Meng, F., & Hughbanks, T.
(2001).
Er(7)Ni(2)Te(2): the most rare-earth metal-rich ternary chalcogenide. Inorganic Chemistry.
40(11), 2482-2483.
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Magliocchi, C., Xie, X., & Hughbanks, T.
(2000).
A cyanide-bridged chain of Mo6Se8 clusters: a product of cyanide-melt cluster synthesis. Inorganic Chemistry.
39(22), 5000-5001.
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Sun, D., & Hughbanks, T
(2000).
Chloroaluminate ionic liquids as reagents for isolating soluble hexanuclear zirconium halide cluster compounds. Inorganic Chemistry.
39(9), 1964-1968.
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Xie, X., & Hughbanks, T
(2000).
Reduced zirconium halide clusters in aqueous solution. Inorganic Chemistry.
39(3), 555-561.
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Kim, J., & Hughbanks, T
(2000).
Synthesis and structures of new ternary aluminum chalcogenides: LiAlSe2, alpha-LiAlTe2, and beta-LiAlTe2. Inorganic Chemistry.
39(14), 3092-3097.
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Kim, J., & Hughbanks, T.
(2000).
Synthesis and structures of ternary chalcogenides of aluminum and gallium with stacking faults: KMQ(2) (M = Al, Ga; Q = Se, Te). Journal of Solid State Chemistry.
149(2), 242-251.
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Xie, X., & Hughbanks, T.
(1999).
Isolation of Reduced Zirconium Chloride Clusters [(Zr6 CCl12 )Cl6 ]4- and [(Zr6 BCl12 )Cl6 ]5- from Acidic Aqueous Solution. Angewandte Chemie International Edition.
38(12), 1777-1779.
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Sun, D., & Hughbanks, T
(1999).
Electrochemistry of Centered Hexanuclear Zirconium Halide Clusters in Ambient-Temperature Chloroaluminate Molten Salts. Inorganic Chemistry.
38(5), 992-997.
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Xie, X., & Hughbanks, T.
(1999).
Isolation of a water-stable B-centered hexazirconium bromide cluster, trans-[(Zr6BBr12)Br4(H2O)3]3. SOLID STATE SCIENCES.
1(7-8), 463-471.
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Kim, J., & Hughbanks, T.
(1999).
Synthesis and structures of new layered ternary manganese selenides: AMnSe(2) (A = Li, Na, K, Rb, Cs) and Na2Mn2Se3. Journal of Solid State Chemistry.
146(1), 217-225.
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Kim, J., Wang, C., & Hughbanks, T.
(1999).
Synthesis and Structures of New Layered Ternary Manganese Tellurides: AMnTe2 (A = K, Rb, Cs), Na3Mn4Te6, and NaMn1.56Te2. Inorganic Chemistry.
38(2), 235-242.
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Xie, .., Reibenspies, J. H., & Hughbanks, T.
(1998).
Probing the Coordination Chemistry of [Zr6BCl12]+: A Cluster Especially Amenable to NMR Study. Journal of the American Chemical Society.
120(44), 11391-11400.
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Kim, J., Wang, C., & Hughbanks, T.
(1998).
Synthesis and structures of new layered ternary manganese tellurides: AMnTe(2) (A = Li, Na). Inorganic Chemistry.
37(7), 1428-+.
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Long, G. J., Hautot, D., Mohan, A., Hughbanks, T., Xie, .., & Grandjean, F.
(1998).
Compounds with Extremely Negative Mssbauer-Effect Isomer Shifts: A Probe of Intermetallic Bonding in Zr6Cl14Fe, LiZr6Cl15Fe, and KZr6Cl15Fe. Journal of the American Chemical Society.
120(46), 12163-12164.
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Wang, C., Eylem, C., & Hughbanks, T.
(1998).
New Layered Zirconium Tellurides: Zr
0.30 ZrTe2 , Zr0.29 Zr2 Te2 As, and NaZr2 Te2 As. Inorganic Chemistry. 37(3), 390-397.
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Harris, J. D., & Hughbanks, T
(1997).
Multinuclear Magnetic Resonance Spectroscopy of Centered Zirconium Halide Clusters. Journal of the American Chemical Society.
119(40), 9449-9459.
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Harris, J. D., & Hughbanks, T.
(1997).
Synthesis and Characterization of the Isocyanide Ligated Centered Zirconium Halide Cluster [(Zr6Be)Cl12(CNXyl)6]. Journal of Cluster Science: including nanoclusters and nanoparticles.
8(4), 521-531.
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Xu, J., Greenblatt, M., Emge, T., Hhn, P., Hughbanks, T., & Tian, Y.
(1996).
Crystal Structure, Electrical Transport, and Magnetic Properties of Niobium Monophosphide. Inorganic Chemistry.
35(4), 845-849.
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Tian, Y., & Hughbanks, T.
(1996).
Extraction and isolation of the Oneelectron Oxidized [(Zr6Be)Cl18]5 and [(Zr6Be)Cl18]4 Clusters from solid state precursors. Zeitschrift fuer Anorganische und Allgemeine Chemie.
622(3), 425-431.
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Wang, C., & Hughbanks, T.
(1996).
New Zr
6 MTe2 (M = Mn, Fe, Co, Ni, Ru, Pt), Zr6 Fe0.6 Se2.4 , and Zr6 Fe0.57 S2.43 Intermetallics: Structural Links between Binary (Zr,Hf)3 M Alloys and Porous Metal-Rich Tellurides. Inorganic Chemistry. 35(24), 6987-6994.
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Hughbanks, T
(1995).
Curiosity-driven research [4]. Chemical and engineering news.
73(49), 5.
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Hughbanks, T.
(1995).
Exploring the metal-rich chemistry of the early transition elements. Journal of Alloys and Compounds.
229(1), 40-53.
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Tian, Y., & Hughbanks, T.
(1995).
Extraction and Isolation of the [(Zr6B)Cl18]5- Cluster from a Solid State Precursor. Inorganic Chemistry.
34(25), 6250-6254.
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Wang, C., Abdon, R. L., Hughbanks, T., & Reibenspies, J.
(1995).
Hf2.64Zr0.36Te4 and MIxZr3Te4 (MI = Na, K, Rb, Cs), new compounds of the Nb3Te4-structure type. Journal of Alloys and Compounds.
226(1-2), 10-18.
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Wang, C., & Hughbanks, T.
(1995).
Main Group Element Size and Substitution Effects on the Structural Dimensionality of Zirconium Tellurides of the ZrSiS Type. Inorganic Chemistry.
34(22), 5524-5529.
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Hughbanks, T., & Tian, Y.
(1995).
On the structure and composition of carbon nitride. Solid State Communications.
96(5), 321-325.
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Abdon, R. L., & Hughbanks, T.
(1995).
Stabilization of Metal-Rich Compounds by Polar-Intermetallic Bonding. Synthesis, Structure, and Bonding in Hf5MTe3 (M = Fe, Co). Journal of the American Chemical Society.
117(40), 10035-10040.
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Runyan, C. E., & Hughbanks, T.
(1994).
Excising Hexanuclear Zirconium Clusters from Solids as a Route to Zirconium Cluster Solution Chemistry. Journal of the American Chemical Society.
116(17), 7909-7910.
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AHN, K. S., HUGHBANKS, T., RATHNAYAKA, K., & NAUGLE, D. G.
(1994).
ELECTRICAL-PROPERTIES OF THE SQUARE-ANTIPRISMATIC CHAIN COMPOUNDS M4BR4OS (M=Y, ER) AND M4TE4Z (M=NB, TA Z=SI, CR, FE, CO). CHEMISTRY OF MATERIALS.
6(4), 418-423.
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Abdon, R. L., & Hughbanks, T.
(1994).
Hf3Te2: A New and Remarkable Layered Compound. Angewandte Chemie International Edition.
33(22), 2328-2330.
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Abdon, R. L., & Hughbanks, T.
(1994).
New Ternary Hafnium Tellurides Hf8Te6M (M = Mn, Fe) Containing M-Centered Tetrakaidecahedra. CHEMISTRY OF MATERIALS.
6(4), 424-428.
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Ungerer, J. R., & Hughbanks, T.
(1993).
The electronic structure of Sc3@C82. Journal of the American Chemical Society.
115(5), 2054-2055.
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Ahn, K., & Hughbanks, T.
(1993).
Single-Crystal Electrical Resistivities of Some Ta-Rich Chalcogenides. Journal of Solid State Chemistry.
102(2), 446-454.
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Tian, Y., & Hughbanks, T.
(1993).
5d Orbital and electronic localization in rare earth diiodides and praseodymium halides, Pr2X5 (X = Br, I). Inorganic Chemistry.
32(4), 400-405.
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Green, M. T., & Hughbanks, T.
(1993).
Electronic structures of nitridometalates: molecular and extended-chain ions. Inorganic Chemistry.
32(24), 5611-5615.
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PAYNE, M. W., DORHOUT, P. K., KIM, S. J., HUGHBANKS, T. R., & CORBETT, J. D.
(1992).
CHAINS OF CENTERED METAL-CLUSTERS WITH A NOVEL RANGE OF DISTORTIONS - PR3I3RU, Y3I3RU, AND Y3I3IR. Inorganic Chemistry.
31(8), 1389-1394.
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Bond, M. R., & Hughbanks, T.
(1992).
Electronic spectra and electronic structures of [Zr6Cl12Z]Cl6n- (Z = Be, B, Fe) clusters. Inorganic Chemistry.
31(24), 5015-5021.
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Yee, K. A., & Hughbanks, T.
(1992).
Semilocalized bonding schemes in extended systems; orbital localization in yttrium chloride (Y2Cl3) and interstitial derivatives. Inorganic Chemistry.
31(9), 1620-1625.
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Yee, K. A., & Hughbanks, T.
(1992).
Spin state stabilities and distortions of the novel trinitridotransition metalate(6-), (M = vanadium, chromium, iron) ions. Inorganic Chemistry.
31(10), 1921-1925.
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Nanjundaswamy, K. S., & Hughbanks, T.
(1992).
Subtleties of structure and bonding in TaSSe and TaNbS solid solutions. Journal of Solid State Chemistry.
98(2), 278-290.
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KIM, S. J., NANJUNDASWAMY, K. S., & HUGHBANKS, T.
(1991).
SINGLE-CRYSTAL STRUCTURE OF TA3S2 - STRUCTURE AND BONDING IN TA6SN (N = 1, 3, 4, 5-QUESTIONABLE) PENTAGONAL-ANTIPRISMATIC CHAIN COMPOUNDS. Inorganic Chemistry.
30(2), 159-164.
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Yee, K. A., & Hughbanks, T.
(1991).
Utility of semilocalized bonding schemes in extended systems: three-center metal-metal bonding in molybdenum sulfide (MoS2), niobium tantalum sulfide bronze (Hx(Nb,Ta)S2), and zirconium sulfide (ZrS). Inorganic Chemistry.
30(10), 2321-2328.
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Hughbanks, T.
(1989).
Bonding in clusters and condensed cluster compounds that extend in one, two and three dimensions. Progress in Solid State Chemistry.
19(4), 329-372.
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Hughbanks, T., & Corbett, J. D.
(1989).
Encapsulation of heavy transition metals in iodide clusters. Synthesis, structure, and bonding of the unusual cluster phase yttrium iodide-ruthenium (Y6I10Ru). Inorganic Chemistry.
28(4), 631-635.
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Hughbanks, T., & Burdett, J. K.
(1988).
Alternative modes of conjugation in onedimensional polymers. Journal of Chemical Physics.
88(2), 1328-1336.
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Hughbanks, T., Rosenthal, G., & Corbett, J. D.
(1988).
Encapsulation of the transition metals chromium through cobalt in zirconium cluster iodides. Journal of the American Chemical Society.
110(5), 1511-1516.
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Hughbanks, T., & Corbett, J. D.
(1988).
Rare-earth-metal iodide clusters centered by transition metals: synthesis, structure, and bonding of R7I12M compounds (R = Sc, Y, Pr, Gd; M = Mn, Fe, Co, Ni). Inorganic Chemistry.
27(12), 2022-2026.
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Kauzlarich, S. M., Hughbanks, T., Corbett, J. D., Klavins, P., & Shelton, R. N.
(1988).
Two extended metal chain compounds, yttrium iodide carbides (Y4I5C and Y6I7C2). Synthesis, structure, properties, and bonding. Inorganic Chemistry.
27(10), 1791-1797.
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Burdett, J. K., Hughbanks, T., Miller, G. J., Richardson, J. W., & Smith, J. V.
(1987).
Structural-electronic relationships in inorganic solids: powder neutron diffraction studies of the rutile and anatase polymorphs of titanium dioxide at 15 and 295 K. Journal of the American Chemical Society.
109(12), 3639-3646.
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Hughbanks, T., Rosenthal, G., & Corbett, J. D.
(1986).
Alloy clusters: the encapsulation of transition metals (manganese, iron, cobalt, nickel) within cluster halides of zirconium and the rare-earth metals. Journal of the American Chemical Society.
108(26), 8289-8290.
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Hughbanks, T.
(1986).
Can M6X8 clusters form intercluster metal metal bonds?. Inorganic Chemistry.
25(9), 1492-1497.
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Wheeler, R. A., Whangbo, M. H., Hughbanks, T., Hoffmann, R., Burdett, J. K., & Albright, T. A.
(1986).
Symmetric vs. asymmetric linear M-X-M linkages in molecules, polymers, and extended networks. Journal of the American Chemical Society.
108(9), 2222-2236.
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Burdett, J. K., Canadell, E., & Hughbanks, T.
(1986).
Symmetry control of the coloring problem: the electronic structure of MB2C2 (M = calcium, lanthanum, ...). Journal of the American Chemical Society.
108(14), 3971-3976.
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Burdett, J. K., & Hughbanks, T.
(1985).
Aspects of metal-metal bonding in early-transition-metal dioxides. Inorganic Chemistry.
24(12), 1741-1750.
-
Hughbanks, T.
(1985).
Superdegenerate electronic energy levels in extended structures. Journal of the American Chemical Society.
107(24), 6851-6859.
-
Canadell, E., Eisenstein, O., & Hughbanks, T.
(1984).
Electronic switching of ring orientation in cyclopentadienyl-bridged polymers. Inorganic Chemistry.
23(16), 2435-2440.
-
Burdett, J. K., & Hughbanks, T.
(1984).
Niobium oxide (NbO) and titanium oxide (TiO): a study of the structural and electronic stability of structures derived from rock salt. Journal of the American Chemical Society.
106(11), 3101-3113.
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Hughbanks, T., & Hoffmann, R.
(1983).
Chains of trans-edge-sharing molybdenum octahedra: metal-metal bonding in extended systems. Journal of the American Chemical Society.
105(11), 3528-3537.
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Hoffmann, R., Hughbanks, T., Kertesz, M., & Bird, P. H
(1983).
Hypothetical metallic allotrope of carbon. Journal of the American Chemical Society.
105(14), 4831-4832.
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Hughbanks, T., & Hoffmann, R.
(1983).
Molybdenum chalcogenides: clusters, chains, and extended solids. The approach to bonding in three dimensions. Journal of the American Chemical Society.
105(5), 1150-1162.
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Hughbanks, T., Hoffmann, R., Whangbo, M. H., Stewart, K. R., Eisenstein, O., & Canadell, E.
(1982).
Electronic origin of the thermochromic effect in 2,2',5,5'-tetramethylbistibole. Journal of the American Chemical Society.
104(14), 3876-3879.
-
Hughbanks, T., & Hoffmann, R
(1982).
The molybdenum selenide (Mo3Se3-).infin. chain. Inorganic Chemistry.
21(9), 3578-3580.
-
Kertsz, M., & Hughbanks, T.
(1981).
Smooth energy-band interpolation with gradient utilization. Physical review B (PRB).
24(12), 6870-6879.
-
Escobedo-Cruz, F. V., & Hughbanks, T.
(2018).
New coordination networks containing trinuclear lanthanide complexes and hexacyanometallates. Dalton Transactions.
47(19), 6831-6841.
-
chapter
-
Hughbanks, T
(2003).
Centred Zirconium Clusters. Comprehensive Coordination Chemistry II.
(pp. 775-784).
Elsevier.
-
Hughbanks, T
(2003).
Centred Zirconium Clusters. Comprehensive Coordination Chemistry II.
(pp. 775-784).
Elsevier.
-
conference paper
-
Escobedo, F. V., & Hughbanks, T. R.
(2014).
Lanthanide cluster compounds and their potential as SMM: Synthesis, structure, and magnetic properties. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
-
Chen, C., & Hughbanks, T. R.
(2011).
Reduced low dimensional rare earth compounds. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
-
Roy, L. E., & Hughbanks, T
(2003).
Rules for Understanding and Designing Novel Molecule-Based Rare-Earth Magnetic Compounds. MRS Online Proceedings Library.
25-30.
-
Wang, C., Kim, J., & Hughbanks, T
(1997).
Synthesis and structure of novel ternary manganese tellurides: MMnTe
2 (M = Li, Na), Na3 Mn4 Te6 , and Na3 Mn4.7 Te6 . MRS Online Proceedings Library. 23-28.
-
KERTESZ, M., & HUGHBANKS, T. R.
(1995).
LOW BANDGAP LADDER POLYMERS. Synthetic Metals.
699-700.
-
Hoffmann, R., Hughbanks, T. R., & Wijeyesekera, S. D
(1982).
ORBITAL INTERACTIONS IN EXTENDED SYSTEMS. Preprints- American Chemical Society Division of Petroleum Chemistry.
580.
-
Escobedo, F. V., & Hughbanks, T. R.
(2014).
Lanthanide cluster compounds and their potential as SMM: Synthesis, structure, and magnetic properties. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY.
Teaching
teaching activities
- CHEM101 Fund Of Chemistry I Instructor
- CHEM107 Gen Chem For Engineers Instructor
- CHEM111 Fund Of Chem Lab I Instructor
- CHEM117 Gen Chem For Engr Lab Instructor
- CHEM119 Fund Of Chemistry I Instructor
- CHEM120 Fund Of Chemistry Ii Instructor
- CHEM468 Mat Chem Inorganic Matls Instructor
- CHEM491 Hnr-research Instructor
- CHEM634 Phys Meth In Inorg Chm Instructor
- CHEM673 Sym & Grp Theory In Chem Instructor
- CHEM681 Seminar Instructor
- CHEM691 Research Instructor
- CHEM697 Methods Teach Chem Lab Instructor
Works By Students
chaired theses and dissertations
-
Chen, Chun-Yu (2014-04). Synthesis, Computations and Characterizations of Low Dimensional Rare-Earth Compounds.
-
Dempsey, Scotty Lee (2014-04). Synthesis, Structure and Characterization Of Polynuclear Rare Earth Alkoxide Clusters.
-
Escobedo Cruz, Francisco Vidal (2016-06). Compounds Comprising Lanthanide Clusters and Their Potential as Molecular Magnets: Synthesis, Structure and Magnetic Properties.
-
Guo, Yuyan (2009-05). Mixed ionic and electronic conducting electrode studies for an alkali metal thermal to electric converter.
-
Roy, Lindsay Elizabeth (2009-06). Rules for understanding rare-earth magnetic compounds.
-
Shen, Jingyi (2005-08). Density functional theory study on the interstitial chemical shifts of main-group-element centered hexazirconium halide clusters; synthetic control of speciation in [(Zr6ZCl12)] (Z = B, C)-based mixed ligand complexes.
-
Sweet, Lucas Edward (2009-05). Synthesis, structure and magnetic properties of lanthanide cluster compounds.
Background
education and training
Contact
first name
- Timothy
has last name
- Hughbanks
mailing address
-
Texas A&M University
Chemistry Department-Adloc
3255 TAMU
College Station, TX 77843-3255
USA
Other
- t-hughbanks@tamu.edu