EQUILIBRIUM-CONSTANTS FOR THE FORMATION OF CU(I) HALIDE-COMPLEXES

abstract

• The stoichiometric equilibrium constants, K 3 *, for the formation of CuX 3 2- from CuX 2 - +X- where X=Cl and Br, have been determined from spectral measurements. The measurements were made in NaCl and NaBr solutions from I=0.5 to 6.0m at 5, 25 and 45C. The measured constants were extrapolated to infinite dilution using the Pitzer equations. The Pitzer parameters, 0, 1 and C, for the interaction of Na+ with CuX 2 - and CuX 3 2- are briefly discussed. 1990 Plenum Publishing Corporation.

authors

• Sharma, Virender

published proceedings

• JOURNAL OF SOLUTION CHEMISTRY

author list (cited authors)

• SHARMA, V. K., & MILLERO, F. J.

citation count

• 29

complete list of authors

• SHARMA, VK||MILLERO, FJ

publication date

• April 1990

publisher

• Springer Nature  Publisher

published in

• Journal of Solution Chemistry  Journal

keywords

• 34 Chemical Sciences
• 3406 Physical Chemistry

Digital Object Identifier (DOI)

• 10.1007/BF00648142

start page

• 375

end page

• 390

volume

• 19

issue

• 4

URL

• http://dx.doi.org/10.1007/bf00648142