Mosssbauer study of the autoxidation of ethylenediaminetetraacetato-ferrate(II)

abstract

• The autoxidation reaction of the Fe2+/ethylenediaminetetraacetic acid system has been studied in solution phase at neutral pH and in solid state using Mssbauer spectroscopy. It was found that despite the proposed reaction pathway consisting of several reaction steps under similar circumstances, no intermediate species could be seen in the Mssbauer spectra and instead of the formation of the well-known [FeIII(EDTA) (H2O)]- species, the direct formation of its dimeric form was observed. 2007 Springer Science+Business Media, LLC.

authors

• Sharma, Virender

published proceedings

• STRUCTURAL CHEMISTRY

author list (cited authors)

• Szilagyi, P. A., Homonnay, Z., Szalay, R., Sharma, V. K., & Vertes, A.

citation count

• 2

complete list of authors

• Szilagyi, Petra Agota||Homonnay, Zoltan||Szalay, Roland||Sharma, Virender K||Vertes, Attila

publication date

• October 2007

publisher

• Springer Nature  Publisher

published in

• Structural Chemistry: computational and experimental studies of chemical and biological systems  Journal

keywords

• Autoxidation
• Ferrous Ethylenediaminetetraacetate
• Mossbauer Spectroscopy

Digital Object Identifier (DOI)

• 10.1007/s11224-007-9210-x

start page

• 717

end page

• 722

volume

• 18

issue

• 5

URL

• http://dx.doi.org/10.1007/s11224-007-9210-x