Formation of iron(VI) in ozonalysis of iron(III) in alkaline solution

abstract

• Here we report the formation of iron in hexavalent state, FeVI O42 - in ozonalysis of iron(III) in alkaline medium. The formation of tetrahedral FeVI O42 - ion is confirmed by UV-Visible and Mssbauer spectroscopic techniques. The value of isomer shift, , of the tetra-oxy anion is consistent with known values for various salts of iron(VI) ion. 2007 Elsevier B.V. All rights reserved.

authors

• Sharma, Virender

published proceedings

• INORGANICA CHIMICA ACTA

author list (cited authors)

• Perfiliev, Y. D., Benko, E. M., Pankratov, D. A., Sharma, V. K., & Dedushenko, S. K.

citation count

• 36

complete list of authors

• Perfiliev, Yurii D||Benko, Elena M||Pankratov, Denis A||Sharma, Virender K||Dedushenko, Sergey K

publication date

• May 2007

publisher

• Elsevier  Publisher

published in

• Inorganica Chimica Acta  Journal

keywords

• Iron(VI)
• Iron(iii)
• Mossbauer Spectroscopy
• Ozone

Digital Object Identifier (DOI)

• 10.1016/j.ica.2006.11.019

start page

• 2789

end page

• 2791

volume

• 360

issue

• 8

URL

• http://dx.doi.org/10.1016/j.ica.2006.11.019