Observation of body centered cubic Cu in Cu/Nb nanolayered composites Academic Article uri icon

abstract

  • The deposition of thin alternating layers of Cu and Nb on Si(100) substrates has been studied by transmission electron microscopy as a function of layer thickness. For layer thickness above 25 , there is a strong texture orientation relationship with the close packed planes of fcc Cu parallel to close packed planes of bcc Nb, forming the so-called Kurdjumov-Sachs orientation relationship. However, at thicknesses of under 12 , the Cu is constrained to grow as a slightly distorted bcc structure. It is thought that, when it reaches a critical thickness between 12 and 20 , the bcc Cu loses coherency and transforms martensitically to the fcc phase, resulting in the observed KurdjumovSachs orientation relationship. Electron energy loss spectroscopy observations indicate a difference of 2 eV in the L3 edge suggesting that the Fermi energy is lower in the constrained bcc form of Cu than in the equilibrium fcc structure.

published proceedings

  • Applied Physics Letters

author list (cited authors)

  • Kung, H., Lu, Y., Griffin, A. J., Nastasi, M., Mitchell, T. E., & Embury, J. D.

complete list of authors

  • Kung, H||Lu, Y-C||Griffin, AJ||Nastasi, M||Mitchell, TE||Embury, JD

publication date

  • October 1997