Dimeric Rh Complexes Supported by a Bridging Phosphido/Bis(Phosphine) PPP Ligand.

abstract

• Rh complexes of a tridentate PPP ligand bearing 1,2-pyrrolediyl linkers have been prepared, including examples with the central P donor being either a phosphine or a phosphide. Three bimetallic Rh complexes containing the diamandoid Rh2P2 core (P = phosphido) have been structurally and spectroscopically characterized. The Rh-Rh interaction in these three dimers was examined by way of structural comparisons and DFT investigations.

authors

• Ozerov, Oleg

published proceedings

• Organometallics

author list (cited authors)

• Cosio, M. N., Lee, S. R., Lai, Q., Bhuvanesh, N., Zhou, J., & Ozerov, O. V.

complete list of authors

• Cosio, Mario N||Lee, Samuel R||Lai, Qingheng||Bhuvanesh, Nattamai||Zhou, Jia||Ozerov, Oleg V

publication date

• May 2024

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organometallics  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

PubMed Central ID

• 38756991

Digital Object Identifier (DOI)

• 10.1021/acs.organomet.3c00492

start page

• 947

end page

• 953

volume

• 43

issue

• 9

URL

• http://dx.doi.org/10.1021/acs.organomet.3c00492