Bridging Homogeneous and Heterogeneous Catalysis: PhosphineFunctionalized MetalOrganic Frameworks Academic Article uri icon

abstract

  • Phosphinefunctionalized metalorganic frameworks (PMOFs) as an emerging class of coordination polymers, have provided novel opportunities for the development of heterogeneous catalysts. Yet, compared with the ubiquitous phosphine systems in homogeneous catalysis, heterogenization of phosphines in MOFs is still at its early stage. In this Minireview, we summarize the synthetic strategies, characterization and catalytic reactions based on the PMOFs reported in literature. In particular, various catalytic reactions are discussed in detail in terms of phosphine ligand structurefunction relationship, including the potential obstacles for future development. Finally, we discuss the possible solutions, including new types of reactions and techniques as the perspectives for the development of PMOF catalysts, highlighting the opportunities and challenges.

published proceedings

  • Angewandte Chemie

author list (cited authors)

  • Chen, W., Cai, P., Zhou, H., & Madrahimov, S. T.

complete list of authors

  • Chen, Wenmiao||Cai, Peiyu||Zhou, Hong-Cai||Madrahimov, Sherzod T

publisher