A single carbon atom controls the geometry and reactivity of CoII(N2S2) complexes. Academic Article uri icon

abstract

  • Three- vs. two-carbon N-to-N connectors give rise to monomeric, tetrahedral N2S2Co(II) (eff = 4.24 BM) or dimeric [(N2S2)Co(II)]2 (diamagnetic) complexes, respectively. Differences in the derivative products of the Lewis acid receivers, W0(CO)3 and W0(CO)4, illustrate nucleophilicity of the thiolate sulfur lone pairs in each case, as well as their structural control.

published proceedings

  • Chem Commun (Camb)

altmetric score

  • 1.75

author list (cited authors)

  • Jana, M., Quiroz, M., & Darensbourg, M. Y.

citation count

  • 0

complete list of authors

  • Jana, Manish||Quiroz, Manuel||Darensbourg, Marcetta Y

publication date

  • January 2024