Synthesis of fluorinated aminium cations coupled with carborane anions for use as strong one-electron oxidants. Academic Article uri icon

abstract

  • Synthesis of a series of hydrocarbon-soluble triarylamines bearing F, CF3, and Br substituents showing quasi-reversible redox events in the 0.59-1.32 V range is reported. Chemical oxidation of the amines was carried out with 0.5PhI(OAc)2/Me3SiX/Na[RCB11Cl11] (X = Cl or OTf, R = H or Me), and a few aminium salts were isolated as pure solids.

published proceedings

  • Dalton Trans

altmetric score

  • 2.5

author list (cited authors)

  • Davidson, J. J., Gunther, S. O., Leong, D. W., & Ozerov, O. V.

citation count

  • 0

complete list of authors

  • Davidson, Jillian J||Gunther, S Olivia||Leong, Derek W||Ozerov, Oleg V

publication date

  • October 2023