Natural acetylenes. Part XXIII. A C 18 polyacetylenic keto-aldehyde related to falcarinone from an Umbellifer ( Pastinaca sativa L.) Academic Article

abstract

• The structure of the polyacetylenic keto-aldehyde {H 2 C= CHCO[CC] 2 CH 2 CH= CH[CH 2 ] 7 CHO} has been determined. It is the first C 18 polyacetylene to be isolated from a plant (Pastinaca sativa L.) of the main polyacetylene-producing families. Its occurrence almost certainly establishes the derivation of the C 17 falcarinone and related compounds and is in harmony with Bu'Lock's hypothesis for the biogenesis of the natural acetylenes.

authors

• Safe, Stephen

published proceedings

• Journal of the Chemical Society Perkin Transactions 1

author list (cited authors)

• Jones, E., Safe, S., & Thaller, V.

citation count

• 14

complete list of authors

• Jones, Ewart RH||Safe, S||Thaller, V

publication date

• December 1966

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• n1472-7781ISSN  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1039/j39660001220

start page

• 1220

end page

• 1221

volume

• 0

issue

• 0

URL

• http://dx.doi.org/10.1039/j39660001220