A highly efficient luminescent Pt2Tl2 chain with a short Tl(I)-Tl(I) interaction. uri icon

abstract

  • The preparation of an unsupported tetranuclear cluster with a linear Pt(0)-Tl(I)-Tl(I)-Pt(0) metal chain is described. The complex shows strong red emission in the solid state, having a quantum yield of 73%. Density functional theory (DFT) and time-dependent DFT calculations show that red emission originated from a platinum to thallium-thallium charge-transfer excited state.

published proceedings

  • Inorg Chem

altmetric score

  • 1

author list (cited authors)

  • Jamali, S., Ashtiani, M. M., Jamshidi, Z., Lalinde, E., Moreno, M. T., Samouei, H., Escudero-Adn, E., & Benet-Buchholz, J.

citation count

  • 14

complete list of authors

  • Jamali, Sirous||Ashtiani, Mona M||Jamshidi, Zahra||Lalinde, Elena||Moreno, M Teresa||Samouei, Hamidreza||Escudero-Adán, Eduardo||Benet-Buchholz, Jordi

publication date

  • October 2013