Metal-Organic Cubane Cage with Trimethylplatinum(IV) Vertices.

abstract

• Herein we describe the synthesis and characterization of the first platinum(IV) metal-organic cage [(Me3PtIV)8(byp)12](OTf)8 (2), in which the organometallic moieties trimethylplatinum(IV) (PtMe3) occupied the corners of a cubane structure and 4,4'-bipyridine ligands used as linkers. The first-principles density functional theory calculations showed that the highest occupied molecular orbitals were localized on the PtMe3 moieties, while the lowest unoccupied molecular orbitals were distributed on the organic linkers.

authors

• Samouei, Hamidreza

published proceedings

• Inorg Chem

altmetric score

• 1.5

author list (cited authors)

• Hendi, Z., Jamali, S., Mahmoudi, S., Samouei, H., Nayeri, S., Chabok, S., & Jamshidi, Z.

citation count

• 0

complete list of authors

• Hendi, Zohreh||Jamali, Sirous||Mahmoudi, Soheil||Samouei, Hamidreza||Nayeri, Sara||Chabok, Seyed Mohamad J||Jamshidi, Zahra

publication date

• January 2022

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

PubMed Central ID

• 34890191

Digital Object Identifier (DOI)

• 10.1021/acs.inorgchem.1c02803

start page

• 15

end page

• 19

volume

• 61

issue

• 1

URL

• http://dx.doi.org/10.1021/acs.inorgchem.1c02803